Ontology highlight
ABSTRACT:
SUBMITTER: Boyd EA
PROVIDER: S-EPMC8891045 | biostudies-literature | 2022 Mar
REPOSITORIES: biostudies-literature
Boyd Emily A EA Hopkins Leseberg Julie A JA Cosner Emma L EL Lionetti Davide D Henke Wade C WC Day Victor W VW Blakemore James D JD
Chemistry (Weinheim an der Bergstrasse, Germany) 20220203 13
Half-sandwich rhodium monohydrides are often proposed as intermediates in catalysis, but little is known regarding the redox-induced reactivity accessible to these species. Herein, the bis(diphenylphosphino)ferrocene (dppf) ligand has been used to explore the reactivity that can be induced when a [Cp*Rh] monohydride undergoes remote (dppf-centered) oxidation by 1e<sup>-</sup> . Chemical and electrochemical studies show that one-electron redox chemistry is accessible to Cp*Rh(dppf), including a u ...[more]