Dataset Information

Controlled synthesis of trimetallic nitrogen-incorporated CoNiFe layered double hydroxide electrocatalysts for boosting the oxygen evolution reaction.

ABSTRACT: The development of non-precious trimetallic electrocatalysts exhibiting high activity and stability is a promising strategy for fabricating efficient electrocatalysts for the oxygen evolution reaction (OER). In this study, trimetallic nitrogen-incorporated CoNiFe (N-CoNiFe) was produced to solve the low OER efficiency using a facile co-precipitation method in the presence of ethanolamine (EA) ligands. A series of CoNiFe catalysts at different EA concentrations were also investigated to determine the effects of the ligand in the co-precipitation of a trimetallic system. The introduction of an optimized EA concentration (20 mM) improved the electrocatalytic performance of N-CoNiFe dramatically, with an overpotential of 318 mV at 10 mA cm^-2 in 1.0 M KOH and a Tafel slope of 72.2 mV dec^-1. In addition, N-CoNiFe shows high durability in the OER process with little change in the overpotential (ca. 16.0 mV) at 10 mA cm^-2 after 2000 cycles, which was smaller than that for commercial Ir/C (38.0 mV).

SUBMITTER: Nguyen ATN

PROVIDER: S-EPMC9044820 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Controlled synthesis of trimetallic nitrogen-incorporated CoNiFe layered double hydroxide electrocatalysts for boosting the oxygen evolution reaction.

Nguyen Anh Thi Nguyet ATN Kim Minji M Shim Jun Ho JH

RSC advances 20220427 20

The development of non-precious trimetallic electrocatalysts exhibiting high activity and stability is a promising strategy for fabricating efficient electrocatalysts for the oxygen evolution reaction (OER). In this study, trimetallic nitrogen-incorporated CoNiFe (N-CoNiFe) was produced to solve the low OER efficiency using a facile co-precipitation method in the presence of ethanolamine (EA) ligands. A series of CoNiFe catalysts at different EA concentrations were also investigated to determine ...[more]

PMID: 35496332

Similar Datasets

Project description:Indiscriminate use of chemical fertilizers leads to soil environmental disbalance and therefore, preparation and application of environment-friendly slow-release multifunctional fertilizers are of paramount importance for sustainable crop production in the present scenario. In this study, we propose a slow-release multifunctional composite nitrogen (N) fertilizer, which possesses the ability to supply plant accessible N in the form of ammonium (NH4 +) and nitrate (NO3 -) to improve nitrate assimilation coupled with zinc (Zn, a major micronutrient for plants in the soil) after its degradation. For this purpose, NO3 --intercalated zinc-aluminum (Zn-Al) layered double hydroxide (LDH) was synthesized using a co-precipitation protocol. The prepared LDH was added as 25.45% of total polymer weight to a sodium carboxymethyl cellulose/hydroxyethyl cellulose citric acid (NaCMC/HEC-CA) biodegradable hydrogel. A. brasilense, commonly used nitrogen-fixing bacteria in soils, was added to the LDH-hydrogel composite along with LDH alone to augment the availability of NH4 + and NO3 -. Adjusting the pH under acidic (pH 5.25) and neutral (pH 7) conditions, the release pattern of NO3 - from LDH and the composite was monitored for 30 days at normal temperature. The pH was selected based on the soil analysis data of North East India. The LDH-composite released 90% (w/w) and 85.45% (w/w) of intercalated NO3 - at pH 5.25 and 7.00 respectively in 30 days. However, 100% (w/w) and 87% (w/w) of intercalated NO3 - at pH 5.25 and 7.00 respectively were released in 30 days when only LDH was applied, which indicated the lower performance of LDH alone in comparison to the LDH-composite for the nitrate holding pattern. The pH of the bacteria-loaded system was observed to be acidic (pH = 5-6) during the study of nitrate assimilation and Zn2+ release. A. brasilense improved nitrate assimilation and increased the NH4 + ion concentration in the studied system. A significant increase in Zn2+ release was observed from day 5 in the presence of A. brasilense in the LDH-composite compared with that in the absence of A. brasilense. In conclusion, the prepared LDH-hydrogel-A. brasilense composite fertilizer system increases the availability of plant accessible N form (both NO3 - and NH4 +) and can potentially improve soil fertility with the addition of Zn and bacteria to the soil in the extended course.

Dataset Information

Controlled synthesis of trimetallic nitrogen-incorporated CoNiFe layered double hydroxide electrocatalysts for boosting the oxygen evolution reaction.

Publications

Controlled synthesis of trimetallic nitrogen-incorporated CoNiFe layered double hydroxide electrocatalysts for boosting the oxygen evolution reaction.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets