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Multilayer carbon materials prepared from Zanthoxylum schinifolium husk for high-performance supercapacitors.

ABSTRACT: In this work, porous carbon mixed with nitrogen (NC) prepared using Zanthoxylum schinifolium husk as a precursor has been successfully applied in a supercapacitor (SC). The effects of KOH dosage on the structure, composition and capacitive properties of the carbon were investigated by a variety of techniques (SEM, HRTEM, XRD, Raman spectroscopy, XPS, BET, and electrochemical tests). The results of physical characterizations also confirmed that NC had a high specific surface area, abundant pores and a large number of heteroatomic functional groups. Meanwhile, the sample exhibits the best electrochemical performance in a 6 M KOH electrolyte, including high specific capacitance (333.7 F g^-1 at a current density of 0.5 A g^-1), desirable rate capability and superior cycling stability (97.9% capacitance retention after 5000 cycles). More importantly, the assembled symmetrical supercapacitor (NC-3//NC-3) holds superior energy density (16.7 W h kg^-1 at a power density of 300.6 W kg^-1) and good cycling stability (98.5% specific capacitance retention after 5000 cycles).

SUBMITTER: Yin H

PROVIDER: S-EPMC9049566 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Multilayer carbon materials prepared from <i>Zanthoxylum schinifolium</i> husk for high-performance supercapacitors.

Yin Haiyan H Zheng Hong H Yang Liu L Wang Shuya S Liu Lian L

RSC advances 20200204 10

In this work, porous carbon mixed with nitrogen (NC) prepared using <i>Zanthoxylum schinifolium</i> husk as a precursor has been successfully applied in a supercapacitor (SC). The effects of KOH dosage on the structure, composition and capacitive properties of the carbon were investigated by a variety of techniques (SEM, HRTEM, XRD, Raman spectroscopy, XPS, BET, and electrochemical tests). The results of physical characterizations also confirmed that NC had a high specific surface area, abundant ...[more]

PMID: 35497464

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Project description:Supercapacitors store energy either by ion adsorption or fast surface redox reactions. The capacitance produced by the former is known as electrochemical double layer capacitance and the latter is known as pseudo-capacitance. Carbon materials are found to be attractive materials for energy storage, due to their various micro-structures and wide source of availability. Polybenzoxazine (Pbz) is used as a source to produce carbon materials, due to the fact that the obtained carbon will be rich in N and O species for enhanced performance. Moreover, the carbon materials were produced via template-free method. In general, activation temperature plays a main role in altering the porosity of the carbon materials. The main purpose of this study is to find the suitable activation temperature necessary to produce porous carbons with enhanced performance. Considering these points, Pbz is used as a precursor to produce nitrogen-doped porous carbons (NRPCs) without using any template. Three different activation temperatures, namely 700, 800 and 900 °C, are chosen to prepare activated porous carbons; NRPC-700, NRPC-800 and NRPC-900. Hierarchical micro-/ meso-/macropores were developed in the porous carbons with respect to different activation temperatures. PBz source is used to produce carbons containing heteroatoms and an activation process is used to produce carbons with desirable pore structures. The surface morphology, pore structure and binding of heteroatoms to the carbon surface were analyzed in detail. NRPCs produced in this way can be used as supercapacitors. Further, electrodes were developed using these NRPCs and their electrochemical performance including capacitance, specific capacitance, galvanic charge/discharge, impedance, rate capability are analyzed. The obtained results showed that the activation temperature of 900 °C, is suitable to produce NRPC with a specific capacitance of 245 F g-1 at a current density of 0.5 A g-1, that are attributed to high surface area, suitable pore structure and presence of heteroatoms.

Project description:The energy storage performances of supercapacitors are expected to be enhanced by the use of nanostructured hierarchically micro/mesoporous hollow carbon materials based on their ultra-high specific surface areas and rapid diffusion of electrolyte ions through the interconnected channels of their mesoporous structures. In this work, we report the electrochemical supercapacitance properties of hollow carbon spheres prepared by high-temperature carbonization of self-assembled fullerene-ethylenediamine hollow spheres (FE-HS). FE-HS, having an average external diameter of 290 nm, an internal diameter of 65 nm, and a wall thickness of 225 nm, were prepared by using the dynamic liquid-liquid interfacial precipitation (DLLIP) method at ambient conditions of temperature and pressure. High temperature carbonization (at 700, 900, and 1100 °C) of the FE-HS yielded nanoporous (micro/mesoporous) hollow carbon spheres with large surface areas (612 to 1616 m2 g-1) and large pore volumes (0.925 to 1.346 cm3 g-1) dependent on the temperature applied. The sample obtained by carbonization of FE-HS at 900 °C (FE-HS_900) displayed optimum surface area and exhibited remarkable electrochemical electrical double-layer capacitance properties in aq. 1 M sulfuric acid due to its well-developed porosity, interconnected pore structure, and large surface area. For a three-electrode cell setup, a specific capacitance of 293 F g-1 at a 1 A g-1 current density, which is approximately 4 times greater than the specific capacitance of the starting material, FE-HS. The symmetric supercapacitor cell was assembled using FE-HS_900 and attained 164 F g-1 at 1 A g-1 with sustained 50% capacitance at 10 A g-1 accompanied by 96% cycle life and 98% coulombic efficiency after 10,000 consecutive charge/discharge cycles. The results demonstrate the excellent potential of these fullerene assemblies in the fabrication of nanoporous carbon materials with the extensive surface areas required for high-performance energy storage supercapacitor applications.

Project description:Waste, in particular, biowaste, can be a valuable source of novel carbon materials. Renewable carbon materials, such as biomass-derived carbons, have gained significant attention recently as potential electrode materials for various electrochemical devices, including batteries and supercapacitors. The importance of renewable carbon materials as electrodes can be attributed to their sustainability, low cost, high purity, high surface area, and tailored properties. Fish waste recovered from the fish processing industry can be used for energy applications and prioritizing the circular economy principles. Herein, a method is proposed to prepare a high surface area biocarbon from glycogen extracted from mussel cooking wastewater. The biocarbon materials were characterized using a Brunauer-Emmett-Teller surface area analyzer to determine the specific surface area and pore size and by scanning electron microscopy coupled with energy-dispersive X-ray analysis, Raman analysis, attenuated total reflectance Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. The electrochemical characterization was performed using a three-electrode system, utilizing a choline chloride-based deep eutectic solvent (DES) as an eco-friendly and sustainable electrolyte. Optimal time and temperature allowed the preparation of glycogen-based carbon materials, with a specific surface area of 1526 m2 g-1, a pore volume of 0.38 cm3 g-1, and an associated specific capacitance of 657 F g-1 at a current density of 1 A g-1, at 30 °C. The optimal material was scaled up to a two-electrode supercapacitor using a DES-based solid-state electrolyte (SSE@DES). This prototype delivered a maximum capacitance of 703 F g-1 at a 1 A g-1 of current density, showing 75% capacitance retention over 1000 cycles, delivering the highest energy density of 0.335 W h kg-1 and power density of 1341 W kg-1. Marine waste can be a sustainable source for producing nanoporous carbon materials to be incorporated as electrode materials in energy storage devices.

Dataset Information

Multilayer carbon materials prepared from Zanthoxylum schinifolium husk for high-performance supercapacitors.

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Multilayer carbon materials prepared from <i>Zanthoxylum schinifolium</i> husk for high-performance supercapacitors.

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