Ultrasensitive barocaloric material for room-temperature solid-state refrigeration.

ABSTRACT: One of the greatest obstacles to the real application of solid-state refrigeration is the huge driving fields. Here, we report a giant barocaloric effect in inorganic NH₄I with reversible entropy changes of [Formula: see text] ∼71 J K^-1 kg^-1 around room temperature, associated with a structural phase transition. The phase transition temperature, T_t, varies dramatically with pressure at a rate of dT_t/dP ∼0.79 K MPa^-1, which leads to a very small saturation driving pressure of ΔP ∼40 MPa, an extremely large barocaloric strength of [Formula: see text] ∼1.78 J K^-1 kg^-1 MPa^-1, as well as a broad temperature span of ∼41 K under 80 MPa. Comprehensive characterizations of the crystal structures and atomic dynamics by neutron scattering reveal that a strong reorientation-vibration coupling is responsible for the large pressure sensitivity of T_t. This work is expected to advance the practical application of barocaloric refrigeration.

SUBMITTER: Ren Q 

PROVIDER: S-EPMC9051211 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature