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Facile synthesis of ordered mesoporous zinc alumina catalysts and their dehydrogenation behavior.

ABSTRACT: Ordered mesoporous Zn/Al₂O₃ materials with varying Zn content were simply prepared via an evaporation-induced self-assembly (EISA) method. Dehydrogenation of isobutane to isobutene was carried out on these materials; an isobutane conversion of 45.0% and isobutene yield of 39.0% were obtained over the 10%Zn/Al₂O₃ catalyst at 580 °C with 300 h^-1 GHSV. The obtained materials with Zn content up to 10% possess large specific surface area and big pore volume and zinc species can be highly dispersed on the surface or incorporated into the framework. The acidity of these catalysts was changed by the introduction of Zn, the decrease of strong acid sites is conducive to the promotion of isobutene selectivity and the weak and medium acidic sites played an important role in isobutane conversion. In addition, these catalysts exhibited good catalytic stability, due to the effective inhibition of coke formation by the ordered mesoporous structure.

SUBMITTER: Cheng M

PROVIDER: S-EPMC9062119 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Facile synthesis of ordered mesoporous zinc alumina catalysts and their dehydrogenation behavior.

Cheng Ming M Zhao Huahua H Yang Jian J Zhao Jun J Yan Liang L Song Huanling H Chou Lingjun L

RSC advances 20190328 17

Ordered mesoporous Zn/Al2O3 materials with varying Zn content were simply prepared via an evaporation-induced self-assembly (EISA) method. Dehydrogenation of isobutane to isobutene was carried out on these materials; an isobutane conversion of 45.0% and isobutene yield of 39.0% were obtained over the 10%Zn/Al2O3 catalyst at 580 °C with 300 h-1 GHSV. The obtained materials with Zn content up to 10% possess large specific surface area a ...[more]

PMID: 35520727

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Project description:Alumina materials have widely been used in industrial fields, such as catalysis and adsorption. However, due to the fast sol-gel process and complicated crystalline-phase transformation, the synthesis of alumina materials with both highly ordered mesostructures and crystallized frameworks remains a great challenge. Herein, we report a novel vesicle-aggregation-assembly strategy to prepare highly ordered mesoporous γ-alumina microspheres with unique shifted double-diamond networks for the first time, by using diblock copolymer poly(ethylene oxide)-b-poly(methyl methacrylate) (PEO-b-PMMA) as a template and aluminum isopropoxide as a precursor in a tetrahydrofuran (THF)/hydrochloric acid binary solvent. During the gradual evaporation of THF and H2O, the as-made Al3+-based gel/PEO-b-PMMA composites can be obtained through a co-assembly process based on the hydrogen bonding interaction between hydroxyl groups of alumina oligomers and PEO segments of the diblock copolymers. The formed composites exhibit a spherical morphology with a wide size distribution (diameter size 1-12 μm). Furthermore, these composite microspheres possess an inverse bicontinuous cubic mesostructure (double diamond, Pn3[combining macron]m) with Al3+-based gel buried in the PEO-b-PMMA matrix in the form of two intertwined but disconnected networks. After a simple calcination at 900 °C in air, the structure of the resultant mesoporous alumina changes to a relatively low symmetry (shifted double diamond, Fd3[combining macron]m), ascribed to the shifting of the two alumina networks due to loss of the templates. Meanwhile, the unit cell size of the alumina mesostructure decreases from ∼131 to ∼95 nm. The obtained ordered mesoporous alumina products retain the spherical morphology and possess ultra-large mesopores (∼72.8 nm), columnar frameworks composed of γ-alumina nanocrystalline particles (crystal size of ∼15 nm) and high thermal stability (up to 900 °C). As a support of Au nanoparticles, the formed Au/mesoporous γ-alumina composite catalysts have been used in the catalytic reduction of 4-nitrophenol with a high kinetic constant k of 0.0888 min-1, implying promising potential as a catalyst support.

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Facile synthesis of ordered mesoporous zinc alumina catalysts and their dehydrogenation behavior.

Publications

Facile synthesis of ordered mesoporous zinc alumina catalysts and their dehydrogenation behavior.

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