Covalently linked benzimidazole-containing reduced graphene oxide/polyaniline nanocomposites as electrode materials.

ABSTRACT: In the present manuscript, we reported the effective synthesis of 1,3-bis(2'-benzimidazolyl)-5-aminobenzene-grafted graphene oxide, followed by reduction, affording covalently linked benzimidazole-containing chemically modified reduced graphene oxide. The prepared material was further coated with polyaniline via in situ polymerization. The prepared material was successfully characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray powder diffraction (XRPD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and thermo-gravimetric analysis (TGA); subsequently, it was subjected to electrochemical analysis using a three-electrode system in dilute acid solutions as electrolytes in terms of cyclic voltammetry (CV), galvanostatic charge-discharge and electrochemical impedance studies. The polyaniline-coated binary composite materials revealed maximum specific capacitance of 823 F g^-1 at 0.2 A g^-1 current density, whereas the value for the chemically modified reduced graphene oxide was 477 F g^-1. The CV curves denoted the pseudocapacitive nature of the electrode materials. The values for the retention of specific capacitance for the electrode materials were 77.5% and 87.9% up to 5000 charge-discharge cycles.

SUBMITTER: Roy A 

PROVIDER: S-EPMC9069584 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature