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Dual-functional SiOC ceramics coating modified carbon fibers with enhanced microwave absorption performance.

ABSTRACT: Multi-functional carbon fiber (CF) based composites have great potential as new-type microwave absorption materials (MAMs). However, it was still a huge challenge to integrate antioxidation and MA properties into CF based composites. Herein, the SiOC ceramics coating modified carbon fibers (SiOC/CFs) were prepared by a polymer precursor pyrolysis method. The X-ray photoelectron spectroscopy (XPS) revealed that the SiOC coating was composed of SiOC, SiO₂, and amorphous carbon phases. The SiOC ceramics as dual-functional coating not only heightened the oxidation temperature from 415 °C to 890 °C, but also highly improved the microwave absorbing ability from -12.60 dB to -47.50 dB. The enhanced MA performance could be attributed to multiple reflections in the cross-linked structure, various polarization relaxation processes, and the favorable impedance matching effect. The SiOC ceramics coating as a semiconductor could suppress the skin effect originating from the cross-linked CF network, thus leading to a favorable impedance matching behavior.

SUBMITTER: Zeng S

PROVIDER: S-EPMC9073367 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Dual-functional SiOC ceramics coating modified carbon fibers with enhanced microwave absorption performance.

Zeng Sifan S Feng Wanlin W Peng Shuyuan S Teng Zhen Z Chen Chen C Zhang Haibin H Peng Shuming S

RSC advances 20190927 53

Multi-functional carbon fiber (CF) based composites have great potential as new-type microwave absorption materials (MAMs). However, it was still a huge challenge to integrate antioxidation and MA properties into CF based composites. Herein, the SiOC ceramics coating modified carbon fibers (SiOC/CFs) were prepared by a polymer precursor pyrolysis method. The X-ray photoelectron spectroscopy (XPS) revealed that the SiOC coating was composed of SiOC, SiO<sub>2</sub>, and amorphous carbon phases. T ...[more]

PMID: 35529384

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Project description:This work presents lightweight epoxy foams loaded with very low weight percentages (≤0.5 wt.%) of carbon fibers (CFs) with different lengths (3 mm, 6 mm, and 12 mm) as broadband microwave absorbing materials for anechoic chamber application. The effect of CF length on microwave absorption, especially on the absorption frequency band, is investigated for frequencies between 1 and 15 GHz. For the elaboration of composites, three different methods-spatula, shear mixing, and ultrasounds-are used for the dispersion of CFs. The observation of these CFs, after the dispersion step, shows a high fiber breakage rate when shear mixing is used, unlike when spatula or ultrasounds methods are used. On the other hand, the characterization of the elaborated composites highlights a correlation between the mixing methods, hence the fiber brakeage, and the measured reflection coefficient (reflection loss) of the composites. As a result, the minimum value of the reflection coefficient is shifted toward the high frequencies when the fiber breakage is observed, suggesting that short CFs absorb at high frequencies while long CFs absorb at low frequencies. Dielectric properties, extracted from the measurement in free space, of composites elaborated with different fiber lengths (3 mm, 6 mm, and 12 mm) confirm that short CFs (3 mm) show maximum losses at high frequencies (around 15 GHz) while long CFs (12 mm) show maximum dielectric losses at low frequencies (below 4 GHz). However, no significant variation is observed on the real part of the relative permittivity, as a function of fiber length, for these porous composites loaded with very low CF rates. A hybrid composite, with a mix of different CF lengths, is prepared and characterized. The simulation of the absorption performance of a pyramidal absorber, based on this hybrid composite, is compared to the one of pyramidal absorber based on composites loaded with a single length of carbon fibers. The pyramidal absorber-based hybrid composite predicts the best absorption performance, especially at the low frequency band. The simulated reflection coefficient of this absorber is less than -12 dB in all the studied frequency range, and less than -40 dB for frequencies higher than 3 GHz. This result confirms the interest of using a mix of carbon fiber lengths to achieve a broadband microwave absorber.

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Dual-functional SiOC ceramics coating modified carbon fibers with enhanced microwave absorption performance.

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Dual-functional SiOC ceramics coating modified carbon fibers with enhanced microwave absorption performance.

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