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Physical characteristics of capacitive carbons derived from the electrolytic reduction of alkali metal carbonate molten salts.

ABSTRACT: Carbons have been synthesized through the reduction of molten carbonate systems under varied conditions. The mechanism and kinetics of carbon electrodeposition has been investigated. Carbon morphologies include amorphous, graphite-like, and spherical aggregate phases. Increased graphitic character is observed in carbons electrodeposited at more cathodic potentials, particularly at higher temperatures. Bonding has been investigated and oxygen functionalised sp² and sp³ structures have been identified. The level of functionalization decreases in carbons with reduced amorphous and increased graphitic character. Thermal decomposition of electrodepositied carbons has been investigated and zero order kinetics have been identified. A relationship has been identified between elevated oxygen functionalization and increased pseudo-capacitance, with carbons deposited at 0.15 A cm^-2 showing capacitances of 400 F g^-1 in 0.5 M H₂SO₄ at sweep rates of 10 mV s^-1.

SUBMITTER: Hughes MA

PROVIDER: S-EPMC9075116 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Physical characteristics of capacitive carbons derived from the electrolytic reduction of alkali metal carbonate molten salts.

Hughes Matthew A MA Bennett Robert D RD Allen Jessica A JA Donne Scott W SW

RSC advances 20191111 63

Carbons have been synthesized through the reduction of molten carbonate systems under varied conditions. The mechanism and kinetics of carbon electrodeposition has been investigated. Carbon morphologies include amorphous, graphite-like, and spherical aggregate phases. Increased graphitic character is observed in carbons electrodeposited at more cathodic potentials, particularly at higher temperatures. Bonding has been investigated and oxygen functionalised sp<sup>2</sup> and sp<sup>3</sup> struc ...[more]

PMID: 35539033

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Project description:As part of an educational exercise designed to introduce school students to the technique of single-crystal X-ray diffraction and enhance their understanding of primary and secondary bonding, a group of nine secondary school students was given the opportunity to prepare new compounds and to solve and refine data collected on the crystalline materials they had prepared. Their investigation of the alkali metal salts of 4-hydroxybenzoic acid (H2hba) yielded nine new compounds and their structures are described in this article. Whilst the salts might be expected to have similar atomic arrangements, there are significant differences in their structures. Although H2hba is a relatively simple organic molecule, it displays remarkable coordinative flexibility, forming ionic solids containing the uncharged molecule, the monoanion Hhba- or the dianion hba2-. A common feature of the structures is their layered arrangement: alternating hydrophilic layers made up of closely packed metal-oxygen polyhedra separated by the hydrophobic component of the hydroxybenzoate linking units. Close packing of these units seems to be a dominant influence in determining the overall structure. The hydroxybenzoate units are usually both parallel and antiparallel with their immediate neighbours, with packing that can be edge-to-face, face-to-face or a mixture of the two. Hydrogen bonding plays a key role in the structure of most compounds and a short strong hydrogen bond (SSHB) is observed in two of the networks. The compounds of 4-hydroxybenzoic acid, C7H6O3, described here are: poly[di-μ-aqua-μ-4-oxidobenzoato-dilithium], [Li2(C7H4O3)(H2O)2]n, 1, poly[triaqua-μ-4-oxidobenzoato-dilithium], [Li2(C7H4O3)(H2O)3]n, 2, poly[μ-4-hydroxybenzoato-lithium], [Li(C7H5O3)]n, 3, catena-poly[4-hydroxybenzoate [[diaquasodium]-di-μ-aqua]], {[Na(H2O)4](C7H5O3)}n, 4, poly[di-μ-aqua-aqua-μ-4-hydroxybenzoato-potassium], [K(C7H5O3)(H2O)3]n, 5, poly[μ-aqua-μ-4-hydroxybenzoato-potassium], [K(C7H5O3)(H2O)]n, 6, poly[aqua-μ-4-hydroxybenzoato-rubidium], [Rb(C7H5O3)(H2O)]n, 7, poly[aqua-μ-4-hydroxybenzoato-caesium], [Cs(C7H5O3)(H2O)]n, 8, poly[[μ-aqua-aqua(μ-4-hydroxybenzoato)(4-hydroxybenzoic acid)sodium] monohydrate], {[Na(C7H5O3)(C7H6O3)(H2O)2]·H2O}n, 9, poly[[(μ-4-hydroxybenzoato)(μ-4-hydroxybenzoic acid)rubidium] monohydrate], {[K(C7H5O3)(C7H6O3)]·H2O}n, 10, and poly[[(μ-4-hydroxybenzoato)(μ-4-hydroxybenzoic acid)rubidium] monohydrate], {[Rb(C7H5O3)(C7H6O3)]·H2O}n, 11.

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Physical characteristics of capacitive carbons derived from the electrolytic reduction of alkali metal carbonate molten salts.

Publications

Physical characteristics of capacitive carbons derived from the electrolytic reduction of alkali metal carbonate molten salts.

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