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Enhanced photocatalytic performance of WON@porous TiO₂ nanofibers towards sunlight-assisted degradation of organic contaminants.

ABSTRACT: In the last few decades, TiO₂ has been widely used in different types of photocatalytic applications. However, the relatively large optical band gap (∼3.2 eV), low charge carrier mobility and consequently its low quantum efficiency limit its photocatalytic activity. Herein, we construct a novel nanostructured heterojunction of WON/TiO₂ nanofibers (NFs) by integration of TiO₂ nanofibers synthesized by electrospinning of a polymer solution containing a titanium(iv) butoxide precursor with WON nanoparticles fabricated via annealing of a WO₃ precursor in dry ammonia at 700 °C. The synthesized photocatalysts were characterized using different spectroscopic techniques. Their photocatalytic performance towards the degradation of methyl orange, methylene blue, and phenol as model contaminants was investigated and the charge transfer process was elucidated and compared to that of a TiO₂/WO₃ heterojunction.

SUBMITTER: Ahmad YH

PROVIDER: S-EPMC9086300 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Enhanced photocatalytic performance of WON@porous TiO2 nanofibers towards sunlight-assisted degradation of organic contaminants.

Ahmad Yahia H YH Mohamed Assem T AT Sliem Mostafa H MH Abdullah Aboubakr M AM Al-Qaradawi Siham Y SY

RSC advances 20180921 57

In the last few decades, TiO2 has been widely used in different types of photocatalytic applications. However, the relatively large optical band gap (∼3.2 eV), low charge carrier mobility and consequently its low quantum efficiency limit its photocatalytic activity. Herein, we construct a novel nanostructured heterojunction of WON/TiO2 nanofibers (NFs) by integration of TiO2 nanofibers synthesized by electrospinning of a polymer solution containing a titanium(iv) ...[more]

PMID: 35547673

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Project description:TiO2 nanofibers were fabricated by combination of sol-gel and electrospinning techniques. Ag-doped TiO2 nanofibers with different Ag contents were prepared by two different methods (in situ electrospinning or wetness impregnation of Ag on TiO2 nanofibers) and heat treated at 500 °C for 2 h under an air or N2 atmosphere. The obtained catalysts were characterized by field emission scanning electron microscopy, X-ray diffraction, photoluminescence, and N2 adsorption analyzed by the Brunauer-Emmett-Teller (BET) method. Photocatalytic glucose conversions with electrospun TiO2 and Ag-doped TiO2 nanofibers for production of high-value products were carried out. From different doping methods, the results indicated that 1 wt % Ag-TiO2 nanofibers prepared by an in situ method with calcination under N2 achieved the highest glucose conversion (85.49%). From several Ag loading contents (i.e., 0, 1, 2, and 4 wt %) in Ag-doped TiO2 nanofibers, the nanofibers exhibited different glucose conversions [in order of 2 wt % (99.65%) > 1 wt % (85.49%) > 4 wt % (77.72%) > 0 wt % (29.64%)]. Arabinose, xylitol, gluconic acid, and formic acid were found as the high-value chemicals with the photocatalytic reaction of TiO2 and Ag-doped TiO2 nanofibers under UVA irradiation. Product yields of each converted chemicals from different photocatalysts from different Ag loading contents showed relatively same trends with the glucose conversion. From all results, it can be concluded that the good characteristics of 2 wt % Ag-TiO2 nanofibers such as the smallest anatase crystallite size (8.25 nm) and the highest specific surface area (S BET = 53.69 m2/g) promoted the highest photocatalytic activity. Additionally, TiO2 and Ag-doped TiO2 nanofibers exhibited higher photocatalytic performance for glucose conversion than commercial TiO2 (P25) and synthesized TiO2 nanoparticles. Finally, Ag-doped TiO2 nanofibers showed recycling ability with high photocatalytic glucose conversion after four-time use.

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Enhanced photocatalytic performance of WON@porous TiO₂ nanofibers towards sunlight-assisted degradation of organic contaminants.

Publications

Enhanced photocatalytic performance of WON@porous TiO<sub>2</sub> nanofibers towards sunlight-assisted degradation of organic contaminants.

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