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Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates.


ABSTRACT: We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields.

SUBMITTER: Wang Y 

PROVIDER: S-EPMC9087285 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates.

Wang Yiying Y   Shen Hongtao H   Qiu Jianhua J   Chen Mengqi M   Song Weimin W   Zhao Mingqin M   Wang Longfei L   Bai Feng F   Wang Hongxia H   Wu Zhiyong Z  

Frontiers in chemistry 20220426


We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields. ...[more]

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