High-performance Electret and Antibacterial Polypropylene Meltblown Nonwoven Materials Doped with Boehmite and ZnO Nanoparticles for Air Filtration
Ontology highlight
ABSTRACT:
SUBMITTER: Han M
PROVIDER: S-EPMC9112261 | biostudies-literature | 2022 Jan
REPOSITORIES: biostudies-literature
Similar Datasets
Project description: Not available
| S-EPMC11679853 | biostudies-literature
Project description:Nonwoven products are widely used in disposable products, such as wipes, diapers, and masks. Microfibers shed from these products in the aquatic and air environment have not been fully described. In the present study, 15 commercial single-use nonwoven products (wipes) and 16 meltblown nonwoven materials produced in a pilot plant were investigated regarding their microfiber generation in aquatic and air environments and compared to selected textile materials and paper tissue materials. Microfibers shed in water were studied using a Launder Ometer equipment (1-65 mg of microfibers per gram material), and microfibers shed in air were evaluated using a dusting testing machine that shakes a piece of the nonwoven back and forth (~ 4 mg of microfibers per gram material). The raw materials and bonding technologies affected the microfiber generation both in water and air conditions. When the commercial nonwovens contained less natural cellulosic fibers, less microfibers were generated. Bonding with hydroentangling and/or double bonding by two different bonding methods could improve the resistance to microfiber generation. Meltblown nonwoven fabrics generated fewer microfibers compared to the other commercial nonwovens studied here, and the manufacturing factors, such as DCD (die-to-collector distance) and air flow rate, affected the tendency of microfiber generation. The results suggest that it is possible to control the tendency of microfiber shedding through the choice of operating parameters during nonwoven manufacturing processes.
| S-EPMC9008397 | biostudies-literature
Project description:Nowadays, polypropylene-based nonwovens are used in many areas, from filtration to medicine. One of the methods for obtaining such materials is melt electrospinning. In some cases, it is especially interesting to produce composite fibers with a high degree of filling. In this work, the influence of the filling degree of isotactic polypropylene with calcium carbonate on the structure and properties of nonwoven materials obtained by melt electrospinning was studied. It was shown that electrospinning is possible, even at a filler content of 50%, while the average diameter of the fibers increases with the growth in the content of calcium carbonate. The addition of sodium stearate significantly reduces the diameter of the fibers (from 10-65 to 2-10 microns) due to reducing viscosity and increasing the electrical conductivity of the melt. Wide-angle X-ray diffraction analysis and IR spectroscopy reveal that the initial polymer and composites are characterized by the presence of stable α-form crystals, while nonwovens show a predominance of smectic mesophase. The addition of calcium carbonate leads to an increase in the hydrophobicity of the composite films, the addition of sodium stearate results in a decrease of hydrophobicity, while all nonwovens demonstrate superhydrophobic properties.
| S-EPMC7764975 | biostudies-literature
Project description:Particulate matter (PM) pollution has become a serious threat to public health, climate and ecosystems. Therefore, filtration materials with high filtration efficiency and low air resistance are in urgent need. Electret filters that can significantly improve filtration efficiency without increasing pressure drop are widely used for air filtration. However, long-term maintenance of the electrical charges on electret filters, particularly at high temperatures and in wet conditions, is still a challenge. Herein, we report the fabrication of a novel electret filter with a fluffy structure, high porosity and satisfactory filtration stability using polypropylene (PP) as the matrix polymer and magnesium stearate (MgSt) as the charge enhancer. Benefiting from the fluffy structure created by melt blown at a large die-to-collector distance (DCD), the pressure drop decreased from 67.0 Pa to 52.9 Pa at an air flow rate of 85 L min-1. Furthermore, the introduction of MgSt changed the crystal structure of the melt blown nonwovens, thus improving the electret properties to achieve a high filtration efficiency of 99.22%, a low pressure drop of 92 Pa and a satisfactory QF of 0.054 Pa-1. In particular, the electret filtration materials exhibited excellent filtration stability and loading performance. Thus, this electret material may become a good candidate for personal protective filtration materials against PM2.5.
| S-EPMC9078473 | biostudies-literature
Project description:Meltblown (MB) nonwovens as air filter materials have played an important role in protecting people from microbe infection in the COVID-19 pandemic. As the pandemic enters the third year in this current global event, it becomes more and more beneficial to develop more functional MB nonwovens with special surface selectivity as well as antibacterial activities. In this article, an antibacterial polypropylene MB nonwoven doped with nano silicon nitride (Si3N4), one of ceramic materials, was developed. With the introduction of Si3N4, both the average diameter of the fibers and the pore diameter and porosity of the nonwovens can be tailored. Moreover, the nonwovens having a single-side moisture transportation, which would be more comfortable in use for respirators or masks, was designed by imparting a hydrophobicity gradient through the single-side superhydrophobic finishing of reactive organic/inorganic silicon coprecipitation in situ. After a nano/micro structural SiO2 precipitation on one side of the fabric surfaces, the contact angles were up to 161.7° from 141.0° originally. The nonwovens were evaluated on antibacterial activity, the result of which indicated that they had a high antibacterial activity when the dosage of Si3N4 was 0.6 wt%. The bacteriostatic rate against E. coli and S. aureus was up to over 96%. Due to the nontoxicity and excellent antibacterial activity of Si3N4, this MB nonwovens are promising as a high-efficiency air filter material, particularly during the pandemic.
| S-EPMC9323961 | biostudies-literature
Project description:How to efficiently treat municipal solid waste (MSW) has become one of the critical solutions in response to the call for "carbon neutrality". Here, the waste polypropylene nonwoven fabric of waste diapers was converted into hierarchical nanoporous biochar (HPBC) through pre-carbonization and activation processes as an ideal precursor for supercapacitors (SCs) with excellent performance. The prepared HPBC-750-4 with an ultrahigh specific surface area (3838.04 m2 g-1) and abundant heteroatomic oxygen (13.25%) and nitrogen (1.16%) codoped porous biochar structure. Given its structural advantages, HPBC-750-4 achieved a specific capacitance of 340.9 F g-1 at a current density of 1 A g-1 in a three-electrode system. Its capacitance retention rate was above 99.2% after 10 000 cycles at a current density of 10 A g-1, which indicated an excellent rate capability and long-term cycling stability. Furthermore, the HPBC-750-4//HPBC-750-4 symmetric SC exhibited a superb energy density of 10.02 W h kg-1 with a power density of 96.15 W kg-1 in a 6 M KOH electrolyte. This work not only demonstrates the enormous potential of waste polypropylene nonwoven fabric in the SC industry but also provides an economically feasible means of managing MSW.
| S-EPMC10472799 | biostudies-literature
Project description:Polypropylene melt-blown nonwoven fabric (PP MNF) masks can effectively block pathogens in the environment from entering the human body. However, the adhesion of surviving pathogens to masks poses a risk of human infection. Thus, embedding safe and efficient antibacterial materials is the key to solving pathogen infection. In this study, stable chlorinated poly(methacrylamide-N,N'-methylenebisacrylamide) polypropylene melt-blown nonwoven fabrics (PP-P(MAA-MBAA)-Cl MNFs) have been fabricated by a simple UV cross-link and chlorination process, and the active chlorine content can reach 3500 ppm. The PP-P(MAA-MBAA)-Cl MNFs show excellent hydrophilic and antibacterial properties. The PP-P(MAA-MBAA)-Cl MNFs could kill all bacteria (both Escherichia coli and Staphylococcus aureus) with only 5 min of contact. Therefore, incorporating PP-P(MAA-MBAA)-Cl MNF as a hydrophilic antimicrobial layer into a four-layer PP-based mask holds great potential for enhancing protection and comfort.
| S-EPMC10648686 | biostudies-literature
Project description:The emergence and re-emergence of antibiotic-resistant bacteria is a potential threat to treating infectious diseases. This study employed a nanometer-scale green synthesis using an extract of Solanum incanum leaves to obtain nanoparticles (NPs) and nanocomposites (NCs) possessing antibacterial properties. The FESEM-EDS elemental mapping analysis proved the novelty of the green synthesis approach in synthesizing a copper-doped ZnO NCs with good dopant distribution. The crystallinity and ZnO bandgap were adjusted by extrinsic copper doping in the ZnO lattice. The optical property adjustments from 3.04 to 2.97 eV for indirect Kubelka-Munk functions were confirmed from DRS-UV-vis analysis. The dopant inclusion in the host lattice was also confirmed by the angle shift on the XRD pattern analysis relative to single ZnO. In addition to doping, the XRD pattern analysis also showed the development of CuO crystals. The lattice fringe values from HRTEM analysis confirmed the existence of both CuO and ZnO crystals with local heterojunctions. Doping and heterojunctions have crucial values in charge transfer and visible light harvesting behaviour, as proved by the PL analysis. The synergistic effects of the doped NCs showed greater antibacterial activity against both Gram-positive and Gram-negative bacteria as a result of more ROS generation through the bacteria-cell-catalyst interaction and release of metal ions. The antioxidant potential of the doped NCs was found to be higher than that of single NPs, using the 2,2-diphenyl-1-picrylhydrazyl free radical scavenging assay and is expected to impart protective effects to the host cells by scavenging destructive free radicals. Thus, the overall analysis leads to the conclusion that the potentiality of synthesized materials has a future outlook for biological applications, especially in the development of antimicrobials to combat antibiotic-resistant bacteria and microbes.
| S-EPMC10440632 | biostudies-literature
Project description: Not available
| S-EPMC11206326 | biostudies-literature
Project description:To research the relationship of micro-structures and antibacterial properties of the titanium-doped ZnO powders and probe their antibacterial mechanism, titanium-doped ZnO powders with different shapes and sizes were prepared from different zinc salts by alcohothermal method. The ZnO powders were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-vis), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected area electron diffraction (SAED), and the antibacterial activities of titanium-doped ZnO powders on Escherichia coli and Staphylococcus aureus were evaluated. Furthermore, the tested strains were characterized by SEM, and the electrical conductance variation trend of the bacterial suspension was characterized. The results indicate that the morphologies of the powders are different due to preparation from different zinc salts. The XRD results manifest that the samples synthesized from zinc acetate, zinc nitrate, and zinc chloride are zincite ZnO, and the sample synthesized from zinc sulfate is the mixture of ZnO, ZnTiO3, and ZnSO4 · 3Zn (OH)2 crystal. UV-vis spectra show that the absorption edges of the titanium-doped ZnO powders are red shifted to more than 400 nm which are prepared from zinc acetate, zinc nitrate, and zinc chloride. The antibacterial activity of titanium-doped ZnO powders synthesized from zinc chloride is optimal, and its minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) are lower than 0.25 g L-1. Likewise, when the bacteria are treated by ZnO powders synthesized from zinc chloride, the bacterial cells are damaged most seriously, and the electrical conductance increment of bacterial suspension is slightly high. It can be inferred that the antibacterial properties of the titanium-doped ZnO powders are relevant to the microstructure, particle size, and the crystal. The powders can damage the cell walls; thus, the electrolyte is leaked from cells.
| S-EPMC4015756 | biostudies-literature