The Lande factors of electrons and holes in lead halide perovskites: universal dependence on the band gap.

ABSTRACT: The Landé or g-factors of charge carriers are decisive for the spin-dependent phenomena in solids and provide also information about the underlying electronic band structure. We present a comprehensive set of experimental data for values and anisotropies of the electron and hole Landé factors in hybrid organic-inorganic (MAPbI₃, MAPb(Br_0.5Cl_0.5)₃, MAPb(Br_0.05Cl_0.95)₃, FAPbBr₃, FA_0.9Cs_0.1PbI_2.8Br_0.2, MA=methylammonium and FA=formamidinium) and all-inorganic (CsPbBr₃) lead halide perovskites, determined by pump-probe Kerr rotation and spin-flip Raman scattering in magnetic fields up to 10 T at cryogenic temperatures. Further, we use first-principles density functional theory (DFT) calculations in combination with tight-binding and k ⋅ p approaches to calculate microscopically the Landé factors. The results demonstrate their universal dependence on the band gap energy across the different perovskite material classes, which can be summarized in a universal semi-phenomenological expression, in good agreement with experiment.

SUBMITTER: Kirstein E 

PROVIDER: S-EPMC9163162 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature