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Arsolyl-supported intermetallic dative bonding.


ABSTRACT: The first examples of late transition metal η5-arsolyls (L = CO, P(OMe)3; R = Ph, Me, Et, SiMe3; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional As → M and polar-covalent (dative) Co → M interactions.

SUBMITTER: Kirk RM 

PROVIDER: S-EPMC9200119 | biostudies-literature |

REPOSITORIES: biostudies-literature

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