Ontology highlight
ABSTRACT:
SUBMITTER: Fang H
PROVIDER: S-EPMC9201899 | biostudies-literature | 2022 Jun
REPOSITORIES: biostudies-literature
Fang Hongyun H Shimada Shigeru S
ACS omega 20220601 23
Reaction of water with in situ generated [(PSiP-R)Ir<sup>I</sup>] (PSiP-R = [{2-(R<sub>2</sub>P)C<sub>6</sub>H<sub>4</sub>}<sub>2</sub>MeSi]<sup>-</sup>; R = cyclohexyl, <i>t</i>Bu or <i>i</i>Pr) from [(PSiP-R)Ir(H)<sub>4</sub>] and <i>tert</i>-butylethylene (tbe) showed high ligand dependency. Oxidative addition of water cleanly proceeded in the reaction of [(PSiP-<i>t</i>Bu)Ir<sup>I</sup>] in THF at room temperature to selectively afford a 16-electron hydrido-hydroxo complex [(PSiP- <sup><i>t< ...[more]