Rapid synthesis of layered K _x MnO₂ cathodes from metal-organic frameworks for potassium-ion batteries.

ABSTRACT: Layered transition metal oxides (LTMOs) are a kind of promising cathode materials for potassium-ion batteries because of their abundant raw materials and high theoretical capacities. However, their synthesis always involves long time calcination at a high temperature, leading to low synthesis efficiency and high energy consumption. Herein, an ultra-fast synthesis strategy of Mn-based LTMOs in minutes is developed directly from alkali-transition metal based-metal-organic frameworks (MOFs). The phase transformation from the MOF to LTMO is systematically investigated by thermogravimetric analysis, variable temperature optical microscopy and X-ray diffraction, and the results reveal that the uniform distribution of K and Mn ions in MOFs promotes fast phase transformation. As a cathode in potassium-ion batteries, the fast-synthesized Mn-based LTMO demonstrates an excellent electrochemical performance with 119 mA h g^-1 and good cycling stability, highlighting the high production efficiency of LTMOs for future large-scale manufacturing and application of potassium-ion batteries.

SUBMITTER: Li A 

PROVIDER: S-EPMC9241981 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature