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Hybrid Lithographic Arbitrary Patterning of TiO2 Nanorod Arrays.


ABSTRACT: In this work, we report a hybrid lithographic method that combines the top-down soft lithography and the bottom-up hydrothermal approach for growing single-crystalline TiO2 nanorod arrays with arbitrary patterns. The arbitrary patterns of TiO2 seeds were obtained through the microcontact printing of the TiO2 seed precursor onto Si substrates using prepatterned poly(dimethylsiloxane) (PDMS) as stamps, followed by a baking process. Afterward, TiO2 nanorod arrays were selectively grown on patterned TiO2 seeds through conventional hydrothermal methods. By controlling the TiO2 seed precursor concentration, the hydrothermal reaction time and temperature and the patterns, the morphology and density of the TiO2 nanorods can be tuned in a controllable manner. Overall, this work provides a new strategy for the low-cost and facile preparation of patterned TiO2 nanorod arrays that has potential applications in micro-nano-optoelectronic devices and other fields.

SUBMITTER: Wang J 

PROVIDER: S-EPMC9245127 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature

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Hybrid Lithographic Arbitrary Patterning of TiO<sub>2</sub> Nanorod Arrays.

Wang Jiabao J   Ji Zhenkai Z   Xu Xiuzhen X   Chen Tiantian T   Chen Bo B   Gao Guohua G   Ma Jiwei J   Nie Xipeng X   Xu Xiaobin X  

ACS omega 20220610 25


In this work, we report a hybrid lithographic method that combines the top-down soft lithography and the bottom-up hydrothermal approach for growing single-crystalline TiO<sub>2</sub> nanorod arrays with arbitrary patterns. The arbitrary patterns of TiO<sub>2</sub> seeds were obtained through the microcontact printing of the TiO<sub>2</sub> seed precursor onto Si substrates using prepatterned poly(dimethylsiloxane) (PDMS) as stamps, followed by a baking process. Afterward, TiO<sub>2</sub> nanoro  ...[more]

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