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Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen.

ABSTRACT: The hydrogen-bonded organic frameworks (HOFs) have gained significant attention due to their various alluring applications in the fascinating field of supramolecular chemistry. Herein, we report the electrocatalytic activity of HOFs toward the hydrogen evolution reaction (HER) by utilizing the molecular adduct of cyanuric and trithiocyanuric acid with various organic substrates (melamine and 4,4'-bipyridine). Both the experimental and theoretical findings provide insights and validate the electrocatalytic activity toward HER applications. This work contributes significantly to designing novel highly efficient metal-free HOF-based electrocatalysts for the HER.

SUBMITTER: Giri L

PROVIDER: S-EPMC9260925 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Hydrogen-Bonded Organic Framework Structure: A Metal-Free Electrocatalyst for the Evolution of Hydrogen.

Giri Lopamudra L Mohanty Bishnupad B Thapa Ranjit R Jena Bikash Kumar BK Pedireddi Venkateswara Rao VR

ACS omega 20220621 26

The hydrogen-bonded organic frameworks (HOFs) have gained significant attention due to their various alluring applications in the fascinating field of supramolecular chemistry. Herein, we report the electrocatalytic activity of HOFs toward the hydrogen evolution reaction (HER) by utilizing the molecular adduct of cyanuric and trithiocyanuric acid with various organic substrates (melamine and 4,4'-bipyridine). Both the experimental and theoretical findings provide insights and validate the electr ...[more]

PMID: 35811884

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