Total Synthesis of Resveratrone and iso-Resveratrone.
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ABSTRACT: The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.
SUBMITTER: Fritsch S
PROVIDER: S-EPMC9278093 | biostudies-literature |
REPOSITORIES: biostudies-literature
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