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Chiral Iodotriptycenes: Synthesis and Catalytic Applications.

ABSTRACT: New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds.

SUBMITTER: Khan N

PROVIDER: S-EPMC9278095 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Chiral Iodotriptycenes: Synthesis and Catalytic Applications.

Khan Nasim N Itaya Katsunori K Wirth Thomas T

ChemistryOpen 20220701 7

New iodotriptycenes, including some chiral derivatives, have been synthesised, and their catalytic potential towards oxidative transformations has been investigated. The enantioselectivities observed in the products using chiral iodotriptycene catalysts are low, probably owing to the large distances between the coordinating groups and the iodine moieties in these compounds. ...[more]

PMID: 35822927

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