Ontology highlight
ABSTRACT:
SUBMITTER: Rostoll-Berenguer J
PROVIDER: S-EPMC9295130 | biostudies-literature | 2022 Jul
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20220705 14
A visible-light photocatalytic radical addition reaction of dihydroquinoxalin-2-ones to trifluoromethyl ketones has been established using Ru(bpy)<sub>3</sub>Cl<sub>2</sub> as photocatalyst, acetonitrile as solvent, and HP Single Blue LED as the source of light. The reaction provides a straightforward approach to the synthesis of dihydroquinoxalin-2-ones bearing a trifluoromethyl-substituted tertiary alcohol moiety in moderate to good yields under mild conditions. ...[more]