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Radical Addition of Dihydroquinoxalin-2-ones to Trifluoromethyl Ketones under Visible-Light Photoredox Catalysis.

ABSTRACT: A visible-light photocatalytic radical addition reaction of dihydroquinoxalin-2-ones to trifluoromethyl ketones has been established using Ru(bpy)₃Cl₂ as photocatalyst, acetonitrile as solvent, and HP Single Blue LED as the source of light. The reaction provides a straightforward approach to the synthesis of dihydroquinoxalin-2-ones bearing a trifluoromethyl-substituted tertiary alcohol moiety in moderate to good yields under mild conditions.

SUBMITTER: Rostoll-Berenguer J

PROVIDER: S-EPMC9295130 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins.

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| S-EPMC4892945 | biostudies-literature

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First use of a divalent lanthanide for visible-light-promoted photoredox catalysis.

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