Mimicking the Oxygen-Evolving Center in Photosynthesis.

ABSTRACT: The oxygen-evolving center (OEC) in photosystem II (PSII) of oxygenic photosynthetic organisms is a unique heterometallic-oxide Mn₄CaO₅-cluster that catalyzes water splitting into electrons, protons, and molecular oxygen through a five-state cycle (S_n, n = 0 ~ 4). It serves as the blueprint for the developing of the man-made water-splitting catalysts to generate solar fuel in artificial photosynthesis. Understanding the structure-function relationship of this natural catalyst is a great challenge and a long-standing issue, which is severely restricted by the lack of a precise chemical model for this heterometallic-oxide cluster. However, it is a great challenge for chemists to precisely mimic the OEC in a laboratory. Recently, significant advances ha

SUBMITTER: Chen Y 

PROVIDER: S-EPMC9302449 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature