Dataset Information

Cationic Covalent Organic Framework with Ultralow HOMO Energy Used as Scaffolds for 5.2 V Solid Polycarbonate Electrolytes.

ABSTRACT: Solid polymer electrolytes (SPEs) have become promising candidate to replace common liquid electrolyte due to highly improved security. However, the practical use of SPEs is still restricted by their decomposition and breakage at the electrode interfacial layer especially at high voltage. Herein, a new cationic covalent organic framework (COF) is designed and synthesized as a reinforced skeleton to resist the constant oxidative decomposition of solid polycarbonate electrolyte, which can stabilize cathode electrolyte interphase layer to develop long-term cycle solid lithium metal battery. The ultralow HOMO energy (-12.55 eV according to density functional theory (DFT) calculations), reflecting its oxidation resistance at positive potential, would be responsible for the high decomposition voltage of 5.2 V versus Li⁺ /Li of solid polycarbonate electrolyte. Furthermore, the smooth surface of interfacial layer and inhibited decomposition reaction at cathode side is confirmed in solid LiCoO₂ cell, which realizes high initial capacity up to 160.3 mAh g^-1 at 0.1 C and greatly improved stability in 4.5 V class solid polymer lithium metal battery with high capacity retention over 200 cycles. This new type of high-voltage resistant solid polymer electrolyte promotes the realization of high-voltage cathode materials and higher energy density lithium metal battery.

SUBMITTER: Liu J

PROVIDER: S-EPMC9313477 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:Here we present a new model for alveolar jaw bone regeneration, which uses human dental pulp cells (hDPCs) combined with tyrosine-derived polycarbonate polymer scaffolds [E1001(1k)] containing beta-tricalcium phosphate (?-TCP) [E1001(1k)/?-TCP]. E1001(1k)/?-TCP scaffolds (5?mm diameter?×?1?mm thickness) were fabricated to fit a 5?mm rat mandibular ramus critical bone defect. Five experimental groups were examined in this study: (1) E1001(1k)/?-TCP scaffolds seeded with a high density of hDPCs, 5.0?×?10(5) hDPCs/scaffold (CH); (2) E1001(1k)/?-TCP scaffolds seeded with a lower density of hDPCs, 2.5?×?10(5) hDPCs/scaffold (CL); (3) acellular E1001(1k)/?-TCP scaffolds (SA); (4) acellular E1001(1k)/?-TCP scaffolds supplemented with 4??g recombinant human bone morphogenetic protein-2 (BMP); and (5) empty defects (EDs). Replicate hDPC-seeded and acellular E1001(1k)/?-TCP scaffolds were cultured in vitro in osteogenic media for 1 week before implantation for 3 and 6 weeks. Live microcomputed tomography (?CT) imaging at 3 and 6 weeks postimplantation revealed robust bone regeneration in the BMP implant group. CH and CL groups exhibited similar uniformly distributed mineralized tissue coverage throughout the defects, but less than the BMP implants. In contrast, SA-treated defects exhibited sparse areas of mineralized tissue regeneration. The ED group exhibited slightly reduced defect size. Histological analyses revealed no indication of an immune response. In addition, robust expression of dentin and bone differentiation marker expression was observed in hDPC-seeded scaffolds, whereas, in contrast, BMP and SA implants exhibited only bone and not dentin differentiation marker expression. hDPCs were detected in 3-week but not in 6-week hDPC-seeded scaffold groups, indicating their survival for at least 3 weeks. Together, these results show that hDPC-seeded E1001(1k)/?-TCP scaffolds support the rapid regeneration of osteo-dentin-like mineralized jaw tissue, suggesting a promising new therapy for alveolar jaw bone repair and regeneration.

Dataset Information

Cationic Covalent Organic Framework with Ultralow HOMO Energy Used as Scaffolds for 5.2 V Solid Polycarbonate Electrolytes.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets