Bidimensional Engineered Amorphous a-SnO₂ Interfaces: Synthesis and Gas Sensing Response to H₂S and Humidity.

ABSTRACT: Two-dimensional (2D) transition metal dichalcogenides (TMDs) and metal chalcogenides (MCs), despite their excellent gas sensing properties, are subjected to spontaneous oxidation in ambient air, negatively affecting the sensor's signal reproducibility in the long run. Taking advantage of spontaneous oxidation, we synthesized fully amorphous a-SnO₂ 2D flakes (≈30 nm thick) by annealing in air 2D SnSe₂ for two weeks at temperatures below the crystallization temperature of SnO₂ (T < 280 °C). These engineered a-SnO₂ interfaces, preserving all the precursor's 2D surface-to-volume features, are stable in dry/wet air up to 250 °C, with excellent baseline and sensor's signal reproducibility to H₂S (400 ppb to 1.5 ppm) and

SUBMITTER: Paolucci V 

PROVIDER: S-EPMC9315963 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature