Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Facile Synthesis of Hierarchical CoSeO₃‧2H₂O Nanoflowers Assembled by Nanosheets as a Novel Anode Material for High-Performance Lithium-Ion Batteries.

ABSTRACT: As novel anodic materials for lithium-ion batteries (LIBs), transitional metal selenites can transform into metal oxide/selenide heterostructures in the first cycle, which helps to enhance the Li⁺ storage performance, especially in terms of high discharge capacity. Herein, well-defined hierarchical CoSeO₃‧2H₂O nanoflowers assembled using 10 nm-thick nanosheets are successfully synthesized via a facile one-step hydrothermal method. When used as anodic materials for LIBs, the CoSeO₃‧2H₂O nanoflowers exhibit a considerably high discharge capacity of 1064.1 mAh g^-1 at a current density of 0.1 A g^-1. In addition, the obtained anode possesses good rate capability and cycling stability. Owing to the superior electrochemical properties, the CoSeO₃‧2H₂O nanoflowers would serve as promising anodic materials for high-performance LIBs.

SUBMITTER: Ji XX

PROVIDER: S-EPMC9320587 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Three-dimensional hierarchical ZnCo2O4@C3N4-B nanoflowers as high-performance anode materials for lithium-ion batteries.

Project description:ZnCo2O4 has become one of the most widely used anode materials due to its good specific capacity, cost-efficiency, high thermal stability and environmental benignity. However, its poor conductivity and cycle stability have limited its practical application in lithium-ion batteries. To overcome these issues, we constructed a 3D nanoflower composite material (ZnCo2O4@C3N4-B) by combining ZnCo2O4 as a framework and B-doped g-C3N4 (g-C3N4-B) as a new carbon source material via a simple hydrothermal method. ZnCo2O4@C3N4-B exhibited exceptional specific capacitance of 919.76 mA h g-1 after 500 cycles at 0.2 A g-1 and a long-term capacity retention of 97.8% after 1000 cycles at 2 A g-1. The high reversible capacity, long cycling life and good rate performance could be attributed to the 3D interconnected architecture and doping of g-C3N4-B. This work provides a simple and general strategy to design high-performance anode materials for lithium-ion batteries to meet the needs of practical applications.

| S-EPMC9056650 | biostudies-literature

CoMn(2)O(4) spinel hierarchical microspheres assembled with porous nanosheets as stable anodes for lithium-ion batteries.

Project description:Herein, we report the feasibility to enhance the capacity and stability of CoMn(2)O(4) anode materials by fabricating hierarchical mesoporous structure. The open space between neighboring nanosheets allows for easy diffusion of the electrolyte. The hierarchical microspheres assembled with nanosheets can ensure that every nanosheet participates in the electrochemical reaction, because every nanosheet is contacted with the electrolyte solution. The hierarchical structure and well interconnected pores on the surface of nanosheets will enhance the CoMn(2)O(4)/electrolyte contact area, shorten the Li(+) ion diffusion length in the nanosheets, and accommodate the strain induced by the volume change during the electrochemical reaction. The last, hierarchical architecture with spherical morphology possesses relatively low surface energy, which results in less extent of self-aggregation during charge/discharge process. As a result, CoMn(2)O(4) hierarchical microspheres can achieve a good cycle ability and high rate capability.

| S-EPMC3523291 | biostudies-literature

Facile synthesis of hierarchical CNF/SnO2/Ni nanostructures via self-assembly process as anode materials for lithium ion batteries.

Project description:Hierarchical carbon nanofibre (CNF)/SnO2/Ni nanostructures of graphitized carbon nanofibres and SnO2 nanocrystallines and Ni nanocrystallines have been prepared via divalent tin-alginate assembly on polyacrylonitrile (PAN) fibres, controlled pyrolysis and ball milling. Fabrication is implemented in three steps: (1) formation of a tin-alginate layer on PAN fibres by coating sodium alginate on PAN in a water medium followed by polycondensation in SnCl2 solution; (2) heat treatment at 450°C in a nitrogen atmosphere; (3) ball milling the mixture of CNF/SnO2 fibres and Ni powder. The CNF/SnO2/Ni nanocomposite exhibits good lithium ion storage capacity and cyclability, providing a facile and low-cost approach for the large-scale preparation of anode materials for lithium ion batteries.

| S-EPMC6030287 | biostudies-literature

Hierarchical non-woven fabric NiO/TiO2 film as an efficient anode material for lithium-ion batteries.

Project description:Hierarchical non-woven fabric NiO/TiO2 film is prepared using a facile two-step synthesis by electrospinning and subsequent hydrothermal reaction to yield TiO2 film decorated with NiO nanosheets. As an anode material for Li-ion batteries, the NiO/TiO2 composite exhibits discharge and charge capacities of 1251.3 and 1284.3 mA h g-1, with good cycling performance and rate capability. Characterization shows that the NiO nanosheets are distributed on the surface of the TiO2 nanofibers. The total specific capacity of NiO/TiO2 is higher than the sum of pure TiO2 and NiO, indicating a positive synergistic effect of TiO2 and NiO on the improvement of electrochemical performance. The results suggest that non-woven fabric NiO/TiO2 film is a promising anode material for lithium ion batteries.

| S-EPMC9069587 | biostudies-literature

Ultrasmall Fe2O3 nanoparticles/MoS2 nanosheets composite as high-performance anode material for lithium ion batteries.

Project description:Coupling ultrasmall Fe2O3 particles (~4.0 nm) with the MoS2 nanosheets is achieved by a facile method for high-performance anode material for Li-ion battery. MoS2 nanosheets in the composite can serve as scaffolds, efficiently buffering the large volume change of Fe2O3 during charge/discharge process, whereas the ultrasmall Fe2O3 nanoparticles mainly provide the specific capacity. Due to bigger surface area and larger pore volume as well as strong coupling between Fe2O3 particles and MoS2 nanosheets, the composite exhibits superior electrochemical properties to MoS2, Fe2O3 and the physical mixture Fe2O3+MoS2. Typically, after 140 cycles the reversible capacity of the composite does not decay, but increases from 829 mA h g-1 to 864 mA h g-1 at a high current density of 2 A g-1. Thus, the present facile strategy could open a way for development of cost-efficient anode material with high-performance for large-scale energy conversion and storage systems.

| S-EPMC5316998 | biostudies-literature

Facile Construction of Porous ZnMn2O4 Hollow Micro-Rods as Advanced Anode Material for Lithium Ion Batteries.

Project description:Spinel ZnMn2O4 is considered a promising anode material for high-capacity Li-ion batteries due to their higher theoretical capacity than commercial graphite anode. However, the insufficient cycling and rate properties seriously limit its practical application. In this work, porous ZnMn2O4 hollow micro-rods (ZMO HMRs) are synthesized by a facile co-precipitation method coupled with annealing treatment. On the basis of electrochemical analyses, the as-obtained samples are first characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and scanning electron microscopy techniques. The influences of different polyethylene glycol 400 (PEG 400) additions on the formation of the hollow rod structure are also discussed. The abundant multi-level pore structure and hollow feature of ZMO HMRs effectively alleviate the volume expansion issue, rendering abundant electroactive sites and thereby guaranteeing convenient Li+ diffusion. Thanks to these striking merits, the ZMO HMRs anode exhibits excellent electrochemical lithium storage performance with a reversible specific capacity of 761 mAh g-1 at a current density of 0.1 A g-1, and a long-cycle specific capacity of 529 mAh g-1 after 1000 cycles at 2.0 A g-1 and keep a remarkable rate capability. In addition, the assembled ZMO HMRs-based full cells deliver an excellent rate capacity, and when the current density returns to 0.05 A g-1, the specific capacity can still reach 105 mAh g-1 and remains at 101 mAh g-1 after 70 cycles, maintaining a material-level energy density of approximately 273 Wh kg-1. More significantly, such striking electrochemical performance highlights that porous ZMO HMRs could be a promising anode candidate material for LIBs.

| S-EPMC9920744 | biostudies-literature

Carbon Nanofibers Decorated by MoS2 Nanosheets with Tunable Quantity as Self-Supporting Anode for High-Performance Lithium Ion Batteries.

Project description:Two-dimensional molybdenum disulfide (MoS2) is considered as a highly promising anode material for lithium-ion batteries (LIBs) due to its unique layer structure, large plane spacing, and high theoretical specific capacity; however, the overlap of MoS2 nanosheets and inherently low electrical conductivity lead to rapid capacity decay, resulting in poor cycling stability and low multiplicative performance. This severely limits its practical application in LIBs. To overcome the above problems, composite fibers with a core//sheath structure have been designed and fabricated. The sheath moiety of MoS2 nanosheets is uniformly anchored by the hydrothermal treatment of the axial of carbon nanofibers derived from an electrospinning method (CNFs//MoS2). The quantity of the MoS2 nanosheets on the CNFs substrates can be tuned by controlling the amount of utilized thiourea precursor. The influence of the MoS2 nanosheets on the electrochemical properties of the composite fibers has been investigated. The synergistic effect between MoS2 and carbon nanofibers can enhance their electrical conductivity and ionic reversibility as an anode for LIBs. The composite fibers deliver a high reversible capacity of 866.5 mA h g-1 after 200 cycles at a current density of 0.5 A g-1 and maintain a capacity of 703.3 mA h g-1 after a long cycle of 500 charge-discharge processes at 1 A g-1.

| S-EPMC10574418 | biostudies-literature

Three-Dimensional Flower-like MoS2 Nanosheets Grown on Graphite as High-Performance Anode Materials for Fast-Charging Lithium-Ion Batteries.

Project description:The demand for fast-charging lithium-ion batteries (LIBs) with long cycle life is growing rapidly due to the increasing use of electric vehicles (EVs) and energy storage systems (ESSs). Meeting this demand requires the development of advanced anode materials with improved rate capabilities and cycling stability. Graphite is a widely used anode material for LIBs due to its stable cycling performance and high reversibility. However, the sluggish kinetics and lithium plating on the graphite anode during high-rate charging conditions hinder the development of fast-charging LIBs. In this work, we report on a facile hydrothermal method to achieve three-dimensional (3D) flower-like MoS2 nanosheets grown on the surface of graphite as anode materials with high capacity and high power for LIBs. The composite of artificial graphite decorated with varying amounts of MoS2 nanosheets, denoted as MoS2@AG composites, deliver excellent rate performance and cycling stability. The 20-MoS2@AG composite exhibits high reversible cycle stability (~463 mAh g-1 at 200 mA g-1 after 100 cycles), excellent rate capability, and a stable cycle life at the high current density of 1200 mA g-1 over 300 cycles. We demonstrate that the MoS2-nanosheets-decorated graphite composites synthesized via a simple method have significant potential for the development of fast-charging LIBs with improved rate capabilities and interfacial kinetics.

| S-EPMC10254478 | biostudies-literature

Facile synthesis of carbon and oxygen vacancy co-modified TiNb6O17 as an anode material for lithium-ion batteries.

Project description:Titanium niobium oxides (TNOs), benefitting from their large specific capacity and Wadsley-Roth shear structure, are competitive anode materials for high-energy density and high-rate lithium-ion batteries. Herein, carbon and oxygen vacancy co-modified TiNb6O17 (A-TNO) was synthesized through a facile sol-gel reaction with subsequent heat treatment and ball-milling. Characterizations indicated that A-TNO is composed of nanosized primary particles, and the carbon content is about 0.7 wt%. The nanoparticles increase the contact area of the electrode and electrolyte and shorten the lithium-ion diffusion distance. The carbon and oxygen vacancies decrease the charge transfer resistance and enhance the Li-ion diffusion coefficient of the obtained anode material. As a result of these advantages, A-TNO exhibits excellent rate performance (208 and 177 mA h g-1 at 10C and 20C, respectively). This work reveals that A-TNO possesses good electrochemical performance and has a facile preparation process, thus A-TNO is believed to be a potential anode material for large-scale applications.

| S-EPMC9053084 | biostudies-literature

Nanoparticle Decorated Ultrathin Porous Nanosheets as Hierarchical Co3O4 Nanostructures for Lithium Ion Battery Anode Materials.

Project description:We report a facile synthesis of a novel cobalt oxide (Co3O4) hierarchical nanostructure, in which crystalline core-amorphous shell Co3O4 nanoparticles with a bimodal size distribution are uniformly dispersed on ultrathin Co3O4 nanosheets. When tested as anode materials for lithium ion batteries, the as-prepared Co3O4 hierarchical electrodes delivered high lithium storage properties comparing to the other Co3O4 nanostructures, including a high reversible capacity of 1053.1 mAhg(-1) after 50 cycles at a current density of 0.2 C (1 C = 890 mAg(-1)), good cycling stability and rate capability.

| S-EPMC4742879 | biostudies-literature