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Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.

ABSTRACT: Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)₂Ni(0) species that are challenging to access otherwise.

SUBMITTER: Day CS

PROVIDER: S-EPMC9345648 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.

Day Craig S CS Do Cuong Dat CD Odena Carlota C Benet-Buchholz Jordi J Xu Liang L Foroutan-Nejad Cina C Hopmann Kathrin H KH Martin Ruben R

Journal of the American Chemical Society 20220713 29

Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes serve as unconventional homogeneous reductants due to their high solubility, modular redox potentials, and formation of insoluble, non-coordinating byproducts. The applicability of these reductants is showcased by accessing low-valent (bipy)2Ni(0) species that ar ...[more]

PMID: 35830190

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