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Ferroelectric/paraelectric superlattices for energy storage.

ABSTRACT: The polarization response of antiferroelectrics to electric fields is such that the materials can store large energy densities, which makes them promising candidates for energy storage applications in pulsed-power technologies. However, relatively few materials of this kind are known. Here, we consider ferroelectric/paraelectric superlattices as artificial electrostatically engineered antiferroelectrics. Specifically, using high-throughput second-principles calculations, we engineer PbTiO₃/SrTiO₃ superlattices to optimize their energy storage performance at room temperature (to maximize density and release efficiency) with respect to different design variables (layer thicknesses, epitaxial conditions, and stiffness of the dielectric layer). We obtain results competitive with the state-of-the-art antiferroelectric capacitors and reveal the mechanisms responsible for the optimal properties.

SUBMITTER: Aramberri H

PROVIDER: S-EPMC9348786 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Ferroelectric/paraelectric superlattices for energy storage.

Aramberri Hugo H Fedorova Natalya S NS Íñiguez Jorge J

Science advances 20220803 31

The polarization response of antiferroelectrics to electric fields is such that the materials can store large energy densities, which makes them promising candidates for energy storage applications in pulsed-power technologies. However, relatively few materials of this kind are known. Here, we consider ferroelectric/paraelectric superlattices as artificial electrostatically engineered antiferroelectrics. Specifically, using high-throughput second-principles calculations, we engineer PbTiO<sub>3< ...[more]

PMID: 35921413

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