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Effect of Multilayered Structure on the Static and Dynamic Properties of Magnetic Nanospheres.

ABSTRACT: The development of flexible and lightweight electromagnetic interference (EMI)-shielding materials and microwave absorbers requires precise control and optimization of core-shell constituents within composite materials. Here, a theoretical model is proposed to predict the static and dynamic properties of multilayered core-shell particles comprised of exchange-coupled layers, as in the case of a spherical iron core coupled to an oxide shell across a spacer layer. The theory of exchange resonance in homogeneous spheres is shown to be a limiting special case of this more general theory. Nucleation of magnetization reversal occurs through either quasi-uniform or curling magnetization processes in core-shell particles, where a purely homogeneous magnetization configuration is forbidden by the multilayered morphology. The energy is minimized through mixing of modes for specific interface conditions, leading to many inhomogeneous solutions, which grow as 2ⁿ with increasing layers, where n represents the number of magnetic layers. The analytical predictions are confirmed using numerical simulations.

SUBMITTER: McKeever C

PROVIDER: S-EPMC9354015 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Effect of Multilayered Structure on the Static and Dynamic Properties of Magnetic Nanospheres.

McKeever Conor C Aziz Mustafa M

ACS applied materials & interfaces 20220725 30

The development of flexible and lightweight electromagnetic interference (EMI)-shielding materials and microwave absorbers requires precise control and optimization of core-shell constituents within composite materials. Here, a theoretical model is proposed to predict the static and dynamic properties of multilayered core-shell particles comprised of exchange-coupled layers, as in the case of a spherical iron core coupled to an oxide shell across a spacer layer. The theory of exchange resonance ...[more]

PMID: 35879264

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Project description:The influence of carbon black (CB) structure and surface area on key rubber properties such as monotonic stress-strain, cyclic stress-strain, and dynamic mechanical behaviors are investigated in this paper. Natural rubber compounds containing eight different CBs were examined at equivalent particulate volume fractions. The CBs varied in their surface area and structure properties according to a wide experimental design space, allowing robust correlations to the experimental data sets to be extracted. Carbon black structure plays a dominant role in defining the monotonic stress-strain properties (e.g., secant moduli) of the compounds. In line with the previous literature, this is primarily due to strain amplification and occluded rubber mechanisms. For cyclic stress-strain properties, which include the Mullins effect and cyclic softening, the observed mechanical hysteresis is strongly correlated with carbon black structure, which implies that hysteretic energy dissipation at medium to large strain values is isolated in the rubber matrix and arises due to matrix overstrain effects. Under small to medium dynamic strain conditions, classical strain dependence of viscoelastic moduli is observed (the Payne effect), the magnitude of which varies dramatically and systematically depending on the colloidal properties of the CB. At low strain amplitudes, both CB structure and surface area are positively correlated to the complex moduli. Beyond ~2% strain amplitude the effect of surface area vanishes, while structure plays an increasing and eventually dominant role in defining the complex modulus. This transition in colloidal correlations reflects the transition in stiffening mechanisms from flexing of rigid percolated particle networks at low strains to strain amplification at medium to high strains. By rescaling the dynamic mechanical data sets to peak dynamic stress and peak strain energy density, the influence of CB colloidal properties on compound hysteresis under strain, stress, and strain energy density control can be estimated. This has considerable significance for materials selection in rubber product development.

Dataset Information

Effect of Multilayered Structure on the Static and Dynamic Properties of Magnetic Nanospheres.

Publications

Effect of Multilayered Structure on the Static and Dynamic Properties of Magnetic Nanospheres.

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