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Fabrication of TiO₂ Spheres and a Visible Light Active α-Fe₂O₃/TiO₂-Rutile/TiO₂-Anatase Heterogeneous Photocatalyst from Natural Ilmenite.

ABSTRACT: High-purity (98.8%, TiO₂) rutile nanoparticles were successfully synthesized using ilmenite sand as the initial titanium source. This novel synthesis method was cost-effective and straightforward due to the absence of the traditional gravity, magnetic, electrostatic separation, ball milling, and smelting processes. Synthesized TiO₂ nanoparticles were 99% pure. Also, highly corrosive environmentally hazardous acid leachate generated during the leaching process of ilmenite sand was effectively converted into a highly efficient visible light active photocatalyst. The prepared photocatalyst system consists of anatase-TiO₂/rutile-TiO₂/Fe₂O₃ (TF-800), rutile-TiO₂/Fe₂TiO₅ (TFTO-800), and anatase-TiO₂/Fe₃O₄ (TF-450) nanocomposites, respectively. The pseudo-second-order adsorption rate of the TF-800 ternary nanocomposite was 0.126 g mg^-1 min^-1 in dark conditions, and a 0.044 min^-1 visible light initial photodegradation rate was exhibited. The TFTO-800 binary nanocomposite adsorbed methylene blue (MB) following pseudo-second-order adsorption (0.224 g mg^-1 min^-1) in the dark, and the rate constant for photodegradation of MB in visible light was 0.006 min^-1. The prepared TF-450 nanocomposite did not display excellent adsorptive and photocatalytic performances throughout the experiment period. The synthesized TF-800 and TFTO-800 were able to degrade 93.1 and 49.8% of a 100 mL, 10 ppm MB dye solution within 180 min, respectively.

SUBMITTER: Usgodaarachchi L

PROVIDER: S-EPMC9366797 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Fabrication of TiO2 Spheres and a Visible Light Active α-Fe2O3/TiO2-Rutile/TiO2-Anatase Heterogeneous Photocatalyst from Natural Ilmenite.

Usgodaarachchi Leshan L Thambiliyagodage Charitha C Wijesekera Ramanee R Vigneswaran Saravanamuthu S Kandanapitiye Murthi M

ACS omega 20220726 31

High-purity (98.8%, TiO2) rutile nanoparticles were successfully synthesized using ilmenite sand as the initial titanium source. This novel synthesis method was cost-effective and straightforward due to the absence of the traditional gravity, magnetic, electrostatic separation, ball milling, and smelting processes. Synthesized TiO2 nanoparticles were 99% pure. Also, highly corrosive environmentally hazardous acid leachate generated during the leaching process of ilmenite sa ...[more]

PMID: 35967057

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Project description:Titanium dioxide is an ubiquitous photocatalyst in water-cleaning technologies, being presently the most promising tools to resolve the global issue of sewage treatment. In this framework, titanium dioxide-graphene nanocomposites are discussed as promising visible-light activated photocatalysts but little is hitherto known about the surface and interface chemistry bridging the metal oxide and carbon phases. In an attempt to spotlight this overlooked issue, we herein designed two different hybrid nanocomposites through covalent grafting and growth of titanium dioxide clusters on graphene oxide and on phosphorylated graphene oxide, which affords GO@TiO2 and PGO@TiO2, respectively. While anatase could be selectively harvested on the surface of GO@TiO2, biphasic anatase-rutile nucleates could be obtained on PGO@TiO2. Thermal annealing treatments improve the metal oxide crystallization and further remove oxygenated groups from the surface of graphene. The interfacial stability of these photocatalysts was also investigated under irradiation, with the graphene support being sensitive to the proximal presence of titanium dioxide. The resulting nanocomposites were also assessed for methylene blue removal through adsorption and photocatalysis. Regardless of their composition, superior photoactivity was noticed for the nanocomposites compared to commercially available degussa that display marginal visible-light photoactivity (11% removal). Within our study, PGO@TiO2-500 stands as the most active catalyst, allowing nearly quantitative removal of the pollutant from water. The superior performance of PGO@TiO2-500 can be explained by the highest stability reached through P-O-Ti bonding, its improved crystallinity, and the reduction of the graphene surface during thermal treatment. On a whole, this study provides a blueprint for comparing semiconducting metal oxide grown on tuneable surface-interfacial graphene environments and highlights the utility of surface-engineering graphene sheets to access efficient visible-light oxidation photocatalysts.

Dataset Information

Fabrication of TiO₂ Spheres and a Visible Light Active α-Fe₂O₃/TiO₂-Rutile/TiO₂-Anatase Heterogeneous Photocatalyst from Natural Ilmenite.

Publications

Fabrication of TiO<sub>2</sub> Spheres and a Visible Light Active α-Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>-Rutile/TiO<sub>2</sub>-Anatase Heterogeneous Photocatalyst from Natural Ilmenite.

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