Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Ferric Chloride-Induced Synthesis of Silver Nanodisks with Considerable Activity for the Reduction of 4-Nitrophenol.

ABSTRACT: Silver nanodisks (AgNDs) have been successfully synthesized by using ferric chloride as an auxiliary agent in the presence of polyvinylpyrrolidone and N,N-dimethylformamide as both a solvent and a reducing agent. The mass ratio of reactants, temperature, and time were demonstrated to be the key factors determining the morphology of the product, and the conversion of Fe³⁺/Fe²⁺ ions played an important role in increasing the ratio of silver nanosheets (AgNSs). As the reaction prolonged, the etching effect of Cl^- ions on the tips of AgNSs became more and more obvious, which made the obtained typical polygonal AgNSs turn into AgNDs eventually. In addition, the prepared AgNDs exhibited a considerable catalytic activity in the reduction of 4-nitrophenol.

SUBMITTER: Chen J

PROVIDER: S-EPMC9404193 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Ferric Chloride-Induced Synthesis of Silver Nanodisks with Considerable Activity for the Reduction of 4-Nitrophenol.

Chen Jie J He Linlin L Fan Zhengyang Z Yang Hongwei H Mao Huaming H Ren Yu Y Yin Jungang J Dai Wei W Cui Hao H

ACS omega 20220812 33

Silver nanodisks (AgNDs) have been successfully synthesized by using ferric chloride as an auxiliary agent in the presence of polyvinylpyrrolidone and N,N-dimethylformamide as both a solvent and a reducing agent. The mass ratio of reactants, temperature, and time were demonstrated to be the key factors determining the morphology of the product, and the conversion of Fe3+/Fe2+ ions played an important role in increasing the ratio of silver nanosheets (AgNSs). A ...[more]

PMID: 36033709

Similar Datasets

Ferric Chloride-induced Murine Thrombosis Models.

Project description:Arterial thrombosis (blood clot) is a common complication of many systemic diseases associated with chronic inflammation, including atherosclerosis, diabetes, obesity, cancer and chronic autoimmune rheumatologic disorders. Thrombi are the cause of most heart attacks, strokes and extremity loss, making thrombosis an extremely important public health problem. Since these thrombi stem from inappropriate platelet activation and subsequent coagulation, targeting these systems therapeutically has important clinical significance for developing safer treatments. Due to the complexities of the hemostatic system, in vitro experiments cannot replicate the blood-to-vessel wall interactions; therefore, in vivo studies are critical to understand pathological mechanisms of thrombus formation. To this end, various thrombosis models have been developed in mice. Among them, ferric chloride (FeCl3) induced vascular injury is a widely used model of occlusive thrombosis that reports platelet activation and aggregation in the context of an aseptic closed vascular system. This model is based on redox-induced endothelial cell injury, which is simple and sensitive to both anticoagulant and anti-platelets drugs. The time required for the development of a thrombus that occludes blood flow gives a quantitative measure of vascular injury, platelet activation and aggregation that is relevant to thrombotic diseases. We have significantly refined this FeCl3-induced vascular thrombosis model, which makes the data highly reproducible with minimal variation. Here we describe the model and present representative data from several experimental set-ups that demonstrate the utility of this model in thrombosis research.

| S-EPMC5091988 | biostudies-literature

Borohydride stabilized gold-silver bimetallic nanocatalysts for highly efficient 4-nitrophenol reduction.

Project description:Bimetallic Au x Ag1-x nanoparticles, prepared using sodium borohydride as the sole reducing and capping agent for various NaBH4 : metal molar ratios, were investigated as catalysts for 4-nitrophenol reduction. This approach yielded the highest catalytic activities observed for this model reaction to date.

| S-EPMC9418733 | biostudies-literature

Heptanuclear Silver Hydride Clusters as Catalytic Precursors for the Reduction of 4-Nitrophenol.

Project description:We report on the design, synthesis, and characterization of the first silver hydride clusters solely protected and stabilized by dithiophosphonate ligands and their application for the in situ generation of silver nanoparticles towards the catalytic reduction of 4-nitrophenol in an aqueous system. The synthesis of the silver monohydride cluster involves the incorporation of an interstitial hydride using sodium borohydride. Poly-nuclear magnetic resonance and mass spectrometry were used to establish the structural properties. The structural properties were then confirmed with a single-crystal X-ray diffraction analysis, which showed a distorted tetracapped tetrahedron core with one hydride ion encapsulated within the core of the silver framework. Additionally, the synthesized heptanuclear silver hydride was utilized as a precursor for the in situ generation of silver nanoparticles, which simultaneously catalyzed the reduction of 4-nitrophenol. The mechanism of the catalytic activity was investigated by first synthesizing AgNPs, which was subsequently used as a catalyst. The kinetic study showed that the pseudo-first constant obtained using the cluster (2.43 × 10-2 s-1) was higher than that obtained using the synthesized AgNPs (2.43 × 10-2 s-1). This indicated that the silver monohydride cluster was more active owing to the release of the encapsulated hydride ion and greater reaction surface prior to aggregation.

| S-EPMC9415167 | biostudies-literature

Dark plasmonic breathing modes in silver nanodisks.

Project description:We map the complete plasmonic spectrum of silver nanodisks by electron energy loss spectroscopy and show that the mode which couples strongest to the electron beam has radial symmetry with no net dipole moment. Therefore, this mode does not couple to light and has escaped from observation in optical experiments. This radial breathing mode has the character of an extended two-dimensional surface plasmon with a wavenumber determined by the circular disk confinement. Its strong near fields can impact the hybridization in coupled plasmonic nanoparticles as well as couplings with nearby quantum emitters.

| S-EPMC3558010 | biostudies-literature

Silver-Nanoparticles Embedded Pyridine-Cholesterol Xerogels as Highly Efficient Catalysts for 4-Nitrophenol Reduction.

Project description:Two xerogels made of 4-pyridyl cholesterol (PC) and silver-nanocomposites (SNCs) thereof have been studied for their efficient reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of aqueous sodium borohydride. Since in-situ silver doping will be effective in ethanol and acetone solvents with a PC gelator, two silver-loaded PC xerogels were prepared and successive SNCs were achieved by using an environmentally benign trisodium citrate dehydrate reducing agent. The formed PC xerogels and their SNCs were comprehensively investigated using different physico-chemical techniques, such as field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), powdered X-ray diffraction (XRD) and UV-Visible spectroscopy (UV-Vis). The FE-SEM results confirm that the shape of xerogel-covered silver nanoparticles (SNPs) are roughly spherical, with an average size in the range of 30-80 nm. Thermal degradation studies were analyzed via the sensitive graphical Broido's method using a TGA technique. Both SNC-PC (SNC-PC-X1 and SNC-PC-X2) xerogels showed remarkable catalytic performances, with recyclable conversion efficiency of around 82% after the fourth consecutive run. The apparent rate constant (kapp) of SNC-PC-X1 and SNC-PC-X2 were found to be 6.120 × 10-3 sec-1 and 3.758 × 10-3 sec-1, respectively, at an ambient temperature.

| S-EPMC7177945 | biostudies-literature

Facile simultaneous synthesis of tetraaniline nanostructures/silver nanoparticles as heterogeneous catalyst for the efficient catalytic reduction of 4-nitrophenol to 4-aminophenol.

Project description:Nanocomposites of tetraaniline (TAN) nanostructures/silver nanoparticles (Ag NPs) were synthesized by an interfacial polymerization method using N-phenyl-1, 4-phenylenediamine (NPPD), AgNO3 and ammonium persulphate (APS) as monomer, oxidizing agent in immiscible solvent toluene-water respectively. The structure and morphology of the as-prepared TAN and Ag NPs were investigated by UV-visible spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and thermogravimetry (TG). The results of FTIR spectroscopy confirmed the formation of TAN and Ag NPs and those of XRD showed the presence of the face centred cubic (fcc) phase of Ag NPs. The FESEM and TEM images gave direct evidence that Ag NPs stabilized with the TAN nanostructures. TGA indicated the enhanced thermal stability of the nanocomposites (NCs). The catalytic activity of TAN/Ag NCs was investigated for the model reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of excess sodium borohydride.

| S-EPMC9054504 | biostudies-literature

Erythrocyte hemolysis and hemoglobin oxidation promote ferric chloride-induced vascular injury.

Project description:The release of redox-active iron and heme into the blood-stream is toxic to the vasculature, contributing to the development of vascular diseases. How iron induces endothelial injury remains ill defined. To investigate this, we developed a novel ex vivo perfusion chamber that enables direct analysis of the effects of FeCl(3) on the vasculature. We demonstrate that FeCl(3) treatment of isolated mouse aorta, perfused with whole blood, was associated with endothelial denudation, collagen exposure, and occlusive thrombus formation. Strikingly exposing vessels to FeCl(3) alone, in the absence of perfused blood, was associated with only minor vascular injury. Whole blood fractionation studies revealed that FeCl(3)-induced vascular injury was red blood cell (erythrocyte)-dependent, requiring erythrocyte hemolysis and hemoglobin oxidation for endothelial denudation. Overall these studies define a unique mechanism of Fe(3+)-induced vascular injury that has implications for the understanding of FeCl(3)-dependent models of thrombosis and vascular dysfunction associated with severe intravascular hemolysis.

| S-EPMC2676043 | biostudies-literature

Synthesis of Au-Pd Bimetallic Nanoflowers for Catalytic Reduction of 4-Nitrophenol.

Project description:Due to the great potential to improve catalytic performance, gold (Au) and palladium (Pd) bimetallic catalysts have prompted structure-controlled synthesis of Au-Pd nanoalloys bounded by high-index facets. In this work, we prepared Au-Pd bimetallic nanoflowers (NFs) with a uniform size, well-defined dendritic morphology, and homogeneous alloy structure in an aqueous solution by seed-mediated synthesis. The prepared bimetallic NFs were fully characterized using a combination of transmission electron microscopy, Ultraviolet-Visible (UV-vis) spectroscopy, inductively coupled plasma optical emission spectroscopy, and cyclic voltammetry measurements. The catalytic activities of the prepared Au-Pd nanoparticles for 4-nitrophenol reduction were also investigated, and the activities are in the order of Au@Pd NFs > Au-Pd NFs (Au₁Pd₁ core) > Au-Pd NFs (Au core), which could be related to the content and exposed different reactive surfaces of Pd in alloys. This result clearly demonstrates that the superior activities of Au-Pd alloy nanodendrites could be attributed to the synergy between Au and Pd in catalysts.

| S-EPMC5618350 | biostudies-literature

Ferric chloride-induced murine carotid arterial injury: A model of redox pathology.

Project description:Ferric chloride (FeCl3) induced vascular injury is a widely used model of occlusive thrombosis that reports platelet activation in the context of an aseptic closed vascular system. This model is based on redox-induced endothelial cell injury, which is simple and sensitive to both anticoagulant and anti-platelets drugs. The time required for platelet aggregation to occlude blood flow gives a quantitative measure of vascular damage that is pathologically relevant to thrombotic disease. We have refined the traditional FeCl3-induced carotid artery model making the data highly reproducible with lower variation. This paper will describe our artifices and report the role of varying the oxidative damage by varying FeCl3 concentrations and exposure. To explore a maximum difference between experimental groups, adjustment of the selected FeCl3 dose and exposure duration may be necessary.

| S-EPMC4116643 | biostudies-literature

Effect of morphologies and compositions of silver-based multicomponent heterogeneous nanocrystals on the reduction of 4-nitrophenol.

Project description:Silver-based nanocrystals have excellent catalytic performance in various reactions, such as the reduction of 4-nitrophenol. The catalytic performance of nanocrystals varies with several parameters, including nanocrystal morphology, composition, and plasmon-induced hot electrons around nanocrystals. Here, highly heterogeneous nanocrystals (Au-Ag and Ag2S-Ag nanocrystals) fabricated on polymer films via a seed-mediated method are used as catalysts for the reduction of 4-nitrophenol, and the effect of the morphology and composition of nanocrystals on the catalytic performance is investigated. These nanocrystals on polymer films exhibit higher reusability (low catalyst loss) in catalytic applications compared to catalysts dispersed freely in the reaction solution. The excellent catalyst performance of these heterogeneous nanocrystals is attributed to their high surface area/volume ratio (flower-like nanocrystals) and strong synergistic effect (cage-like nanocrystals). These nanocrystals with special morphologies and composites showed higher catalytic performance (higher reactivity at lower catalyst contents) than silver-based nanocrystals reported in the literature. Due to the excellent plasmonic properties of Ag nanocrystals, the catalytic performance of these nanocrystals can be further enhanced by generating hot electrons around the nanocrystals under irradiation. These results demonstrated that by carefully controlling the morphology and composition of nanocrystals, it is possible to design and fabricate excellent catalysts for various reactions.

| S-EPMC10496911 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data