Aligned macrocycle pores in ultrathin films for accurate molecular sieving.

ABSTRACT: Polymer membranes are widely used in separation processes including desalination¹, organic solvent nanofiltration^2,3 and crude oil fractionation^4,5. Nevertheless, direct evidence of subnanometre pores and a feasible method of manipulating their size is still challenging because of the molecular fluctuations of poorly defined voids in polymers⁶. Macrocycles with intrinsic cavities could potentially tackle this challenge. However, unfunctionalized macrocycles with indistinguishable reactivities tend towards disordered packing in films hundreds of nanometres thick^7-9, hindering cavity interconnection and formation of through-pores. Here, we synthesized selectively functionalized macrocycles with differentiated reactivities that preferenti

SUBMITTER: Jiang Z 

PROVIDER: S-EPMC9433321 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature