Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Constructing atomically-dispersed Mn on ZIF-derived nitrogen-doped carbon for boosting oxygen reduction.

ABSTRACT: Exploring durable and highly-active non-noble-metal nanomaterials to supersede Pt-based nanomaterials is an effective way, which can reduce the cost and boost the catalytic efficiency of oxygen reduction reaction (ORR). Herein, we constructed atomically-dispersed Mn atoms on the ZIF-derived nitrogen-doped carbon frameworks (Mn-N_x/NC) by stepwise pyrolysis. The Mn-N_x/NC relative to pure nitrogen-doped carbon (NC) exhibited superior electrocatalytic activity with a higher half-wave potential (E _1/2 = 0.88 V) and a modest Tafel slope (90 mV dec^-1) toward ORR. The enhanced ORR performance of Mn-N_x/NC may be attributed to the existence of Mn-N_x active sites, which can more easily adsorb intermediates, promoting the efficiency of ORR. This work provides a facile route to synthesize single-atom catalysts for ORR.

SUBMITTER: Deng Y

PROVIDER: S-EPMC9454009 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Constructing atomically-dispersed Mn on ZIF-derived nitrogen-doped carbon for boosting oxygen reduction.

Deng Yaoyao Y Pang Jiazheng J Ge Wenzheng W Zhang Minxi M Zhang Wentao W Zhang Wei W Xiang Mei M Zhou Quanfa Q Bai Jirong J

Frontiers in chemistry 20220825

Exploring durable and highly-active non-noble-metal nanomaterials to supersede Pt-based nanomaterials is an effective way, which can reduce the cost and boost the catalytic efficiency of oxygen reduction reaction (ORR). Herein, we constructed atomically-dispersed Mn atoms on the ZIF-derived nitrogen-doped carbon frameworks (Mn-N<sub>x</sub>/NC) by stepwise pyrolysis. The Mn-N<sub>x</sub>/NC relative to pure nitrogen-doped carbon (NC) exhibited superior electrocatalytic activity with a higher hal ...[more]

PMID: 36092675

Similar Datasets

Boosting Nitrogen Reduction Reaction via Electronic Coupling of Atomically Dispersed Bismuth with Titanium Nitride Nanorods.

Project description:Electrocatalytic nitrogen reduction reaction (NRR) is a promising alternative to the traditional Haber-Bosch process. However, the sluggish kinetics and competitive hydrogen evolution reaction result in poor NH3 yield and low Faradaic efficiency (FE). Herein, single bismuth atoms incorporated hollow titanium nitride nanorods encapsulated in nitrogen-doped carbon layer (NC) supported on carbon cloth (NC/Bi SAs/TiN/CC) is constructed for electrocatalytic NRR. Impressively, as an integrated electrode, it exhibits a superior ammonia yield rate of 76.15 µg mgcat -1 h-1 (9859 µg μmolBi -1 h-1 ) at -0.8 V versus RHE and a high FE of 24.60% at -0.5 V versus RHE in 0.1 m Na2 SO4 solution, which can retain stable performance in 10 h continuous operation, surpassing the overwhelming majority of reported Bi-based NRR catalysts. Coupling various characterizations with theory calculations, it is disclosed that the unique monolithic core-shell configuration with porous structure endows abundant accessible active sites, outstanding charge-transfer property, and good stability, while the cooperation effect of Bi SAs and TiN can simultaneously promote the hydrogenation of N2 into NH3 * on the TiN surface and the desorption of NH3 * to release NH3 on the Bi SA sites. These features result in the significant promotion of NRR performance.

| S-EPMC8811825 | biostudies-literature

Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nanosheets for lithium-oxygen batteries.

Project description:Developing single-site catalysts featuring maximum atom utilization efficiency is urgently desired to improve oxidation-reduction efficiency and cycling capability of lithium-oxygen batteries. Here, we report a green method to synthesize isolated cobalt atoms embedded ultrathin nitrogen-rich carbon as a dual-catalyst for lithium-oxygen batteries. The achieved electrode with maximized exposed atomic active sites is beneficial for tailoring formation/decomposition mechanisms of uniformly distributed nano-sized lithium peroxide during oxygen reduction/evolution reactions due to abundant cobalt-nitrogen coordinate catalytic sites, thus demonstrating greatly enhanced redox kinetics and efficiently ameliorated over-potentials. Critically, theoretical simulations disclose that rich cobalt-nitrogen moieties as the driving force centers can drastically enhance the intrinsic affinity of intermediate species and thus fundamentally tune the evolution mechanism of the size and distribution of final lithium peroxide. In the lithium-oxygen battery, the electrode affords remarkably decreased charge/discharge polarization (0.40 V) and long-term cyclability (260 cycles at 400 mA g-1).

| S-EPMC7101366 | biostudies-literature

Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst.

Project description:Single-atom catalysts (SACs) with metal-nitrogen (M-N) sites are one of the most promising electrocatalysts for electrochemical carbon dioxide reduction (ECO2R). However, challenges in simultaneously enhancing the activity and selectivity greatly limit the efficiency of ECO2R due to the improper interaction of reactants/intermediates on these catalytic sites. Herein, we report a carbon-based nickel (Ni) cluster catalyst containing both single-atom and cluster sites (NiNx-T, T = 500-800) through a ligand-mediated method and realize a highly active and selective electrocatalytic CO2R process. The catalytic performance can be regulated by the dispersion of Ni-N species via controlling the pyrolysis condition. Benefitting from the synergistic effect of pyrrolic-nitrogen coordinated Ni single-atom and cluster sites, NiNx-600 exhibits a satisfying catalytic performance, including a high partial current density of 61.85 mA cm-2 and a high turnover frequency (TOF) of 7,291 h-1 at -1.2 V vs. RHE, and almost 100% selectivity toward carbon monoxide (CO) production, as well as good stability under 10 h of continuous electrolysis. This work discloses the significant role of regulating the coordination environment of the transition metal sites and the synergistic effect between the isolated single-site and cluster site in enhancing the ECO2R performance.

| S-EPMC8811444 | biostudies-literature

Author Correction: Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nanosheets for lithium-oxygen batteries

Project description: Not available

| S-EPMC9522645 | biostudies-literature

Atomically Dispersed Mn Boosting Photoelectrochemical SARS-CoV-2 Spike Protein Immunosensing on Carbon Nitride.

Project description:The sudden outbreak of coronavirus disease (COVID-19) triggered by SARS-CoV-2 infection has created a terrifying situation around the world. The Spike protein of SARS-CoV-2 may act as an early biomarker for leading to receptor binding and virus entry. Therefore, controlling the spread of COVID-19 requires a low-cost, fast-response, and sensitive monitoring technique of spike protein. Herein, a photoelectrochemical (PEC) immunosensor for the detection of spike protein was constructed using the nanobody and an Mn (Ⅱ) modified graphitic carbon nitride (Mn/g-C3N4). The introduction of atomically dispersed Mn (Ⅱ) accelerates the effective transfer and separation of photogenerated electron-hole pairs, which significantly boosts PEC performance of g-C3N4, thereby improving the detection sensitivity. As a recognition site, nanobody can achieve high-affinity binding to the spike protein for detection. The linear detection range of the proposed PEC immunosensor was 75 fg mL-1 to 150 pg mL-1, and the limit of detection was calculated to be 1.22 fg mL-1. This stable and feasible PEC immunosensor is a promising diagnostic tool for sensitively detecting SARS-CoV-2 spike protein.

| S-EPMC9528068 | biostudies-literature

Mesoporous Nitrogen-Doped Carbon Support from ZIF-8 for Pt Catalysts in Oxygen Reduction Reaction.

Project description:Zeolitic imidazolate framework-8 (ZIF-8) has been extensively studied as a precursor for nitrogen-doped carbon (NC) materials due to its high surface area, tunable porosity, and adjustable nitrogen content. However, the intrinsic microporous structure of the ZIF-8 limits mass transport and accessibility of reactants to active sites, reducing its effectiveness in electrochemical applications. In this study, a soft templating approach using a triblock copolymer was used to prepare mesoporous ZIF-8-derived NC (Meso-ZIF-NC) samples. The hierarchical porous structure was investigated by varying the ratios of Pluronic F-127, NaClO4, and toluene. The resulting Meso-ZIF-NC exhibited widespread pore size distribution with an enhanced mesopore (2-50 nm) volume according to the composition of the reaction mixtures. Pt nanoparticles were uniformly dispersed on the Meso-ZIF-NC to form Pt/Meso-ZIF-NC catalysts, which presented a high electrochemical surface area and improved oxygen reduction reaction activity. The study highlights the important role of mesopore structure and nitrogen doping in enhancing catalytic performance, providing a pathway for advanced fuel cell catalyst design.

| S-EPMC11767951 | biostudies-literature

Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity.

Project description:As low-cost electrocatalysts for oxygen reduction reaction applied to fuel cells and metal-air batteries, atomic-dispersed transition metal-nitrogen-carbon materials are emerging, but the genuine mechanism thereof is still arguable. Herein, by rational design and synthesis of dual-metal atomically dispersed Fe,Mn/N-C catalyst as model object, we unravel that the O2 reduction preferentially takes place on FeIII in the FeN4 /C system with intermediate spin state which possesses one eg electron (t2g4eg1) readily penetrating the antibonding π-orbital of oxygen. Both magnetic measurements and theoretical calculation reveal that the adjacent atomically dispersed Mn-N moieties can effectively activate the FeIII sites by both spin-state transition and electronic modulation, rendering the excellent ORR performances of Fe,Mn/N-C in both alkaline and acidic media (halfwave positionals are 0.928 V in 0.1 M KOH, and 0.804 V in 0.1 M HClO4), and good durability, which outperforms and has almost the same activity of commercial Pt/C, respectively. In addition, it presents a superior power density of 160.8 mW cm-2 and long-term durability in reversible zinc-air batteries. The work brings new insight into the oxygen reduction reaction process on the metal-nitrogen-carbon active sites, undoubtedly leading the exploration towards high effective low-cost non-precious catalysts.

| S-EPMC7979714 | biostudies-literature

Atomically Dispersed Pentacoordinated-Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction.

Project description:Single-atom catalysts (SACs), as promising alternatives to Pt-based catalysts, suffer from the limited choice of center metals and low single-atom loading. Here, we report a pentacoordinated Zr-based SAC with nontrivial axial O ligands (denoted O-Zr-N-C) for oxygen reduction reaction (ORR). The O ligand downshifts the d-band center of Zr and confers Zr sites with stable local structure and proper adsorption capability for intermediates. Consequently, the ORR performance of O-Zr-N-C prominently surpasses that of commercial Pt/C, achieving a half-wave potential of 0.91 V vs. reversible hydrogen electrode and outstanding durability (92 % current retention after 130-hour operation). Moreover, the Zr site shows good resistance towards aggregation, enabling the synthesis of Zr-based SAC with high loading (9.1 wt%). With the high-loading catalyst, the zinc-air battery (ZAB) delivers a record-high power density of 324 mW cm-2 among those of SAC-based ZABs.

| S-EPMC9543759 | biostudies-literature

A doping-adsorption-pyrolysis strategy for constructing atomically dispersed cobalt sites anchored on a N-doped carbon framework as an efficient bifunctional electrocatalyst for hydrogen evolution and oxygen reduction.

Project description:Renewable energy technology development focuses on the exploration of economical and efficient non-precious metal catalysts to replace precious metal catalysts in electrocatalytic reactions including oxygen reduction (ORR) and hydrogen evolution (HER). Herein, we synthesized a cobalt single atom catalyst anchored on a N-doped carbon framework by a doping-adsorption-pyrolysis strategy. The optimized Co SAs/CN-3 catalyst showed excellent HER and ORR bifunctional electrocatalytic performance, which could be attributed to the highly dispersed Co-N4 active sites, large specific surface area and abundant pore structure. Density functional theory shows that the isolated active Co-N4 site shows low hydrogen adsorption Gibbs free energy, and promotes the adsorption of H and oxygen-containing intermediates in HER and ORR. This work not only provides a new idea for the construction of transition metal catalysts with atomic accuracy but also provides powerful guidance for the development of efficient bifunctional electrocatalysts.

| S-EPMC9284523 | biostudies-literature

Atomically dispersed Zn-Co-N-C catalyst boosting efficient and robust oxygen reduction catalysis in acid via stabilizing Co-N bonds.

Project description:Transition metal supported N-doped carbon (M-N-C) catalysts for oxygen reduction reaction (ORR) are viewed as the promising candidate to replace Pt-group metal (PGM) for proton exchange membrane fuel cells (PEMFCs). However, the stability of M-N-C is extremely challenging due to the demetalation, H2O2 attack, etc. in the strongly oxidative conditions of PEMFCs. In this study, we demonstrate the universal effect of Zn on promoting the stability of atomically dispersed M-Nx/C (M = Co, Fe, Mn) catalysts and the enhancement mechanism is unveiled for the first time. The best-performing dual-metal-site Zn-Co-N-C catalyst exhibits a high half-wave potential (E 1/2) value of 0.81 V vs. reversible hydrogen electrode (RHE) in acid and outstanding durability with no activity decay after 15,000 accelerated degradation test (ADT) cycles at 60 °C, surpassing most reported Co-based PGM-free catalysts in acid media. For comparison, the Co-N-C in the absence of Zn suffers from a rapid degradation after ADT due to the demetalation and higher H2O2 yield. X-ray adsorption spectroscopy (XAS) and density functional theory (DFT) calculations suggest the more negative formation energy (by 1.2 eV) and increased charge transfer of Zn-Co dual-site structure compared to Co-N-C could strength the Co-N bonds against the demetalation and the optimized d-band center accounts for the improved ORR kinetics.

| S-EPMC11197814 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data