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N-(4-Meth-oxy-2-nitro-phen-yl)acetamide.

ABSTRACT: In the title compound, C₉H₁₀N₂O₄, the three substituents vary in the degree of lack of planarity with the central phenyl ring. The meth-oxy group is nearest to being coplanar, with a C-C-O-C torsion angle of 6.1 (5)°. The nitro group is less coplanar, with a 12.8 (5)° twist about the C-N bond and the acetamido group is considerably less coplanar with the central ring, having a 25.4 (5)° twist about the C-N bond to the ring. The NH group forms an intra-molecular N-H⋯O hydrogen bond to a nitro-group O atom.

SUBMITTER: Hines Iii JE

PROVIDER: S-EPMC9462018 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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N-(4-Meth-oxy-2-nitro-phen-yl)acetamide.

Hines Iii James E JE Deere Curtistine J CJ Vaddi Poornasai P Kondati Ranjeeth R RR Fronczek Frank R FR Uppu Rao M RM

IUCrData 20220317 Pt 3

In the title compound, C9H10N2O4, the three substituents vary in the degree of lack of planarity with the central phenyl ring. The meth-oxy group is nearest to being coplanar, with a C-C-O-C torsion angle of 6.1 (5)°. The nitro group is less coplanar, with a 12.8 (5)° twist about the C-N bond and the acetamido group is considerably less coplanar with the central ring, having a 25.4 (5)° twist about the C-N bond to the ring. The NH group forms an intra- ...[more]

PMID: 36339804

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