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([2.2.2]Cryptand)potassium (4-methyl-benzene-thiol-ato)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyr-inato]manganate(II) tetra-hydro-furan disolvate.

ABSTRACT: Single crystals of the title compound, [K(C18H36N2O6)][Mn(C44H24Cl4N4)(C7H7S)]·2C4H8O, were obtained by the solvent evaporation method. The MnII cation is coordinated by four pyrrole N atoms (Np) of the porphyrin ring and one S atom of the apical 4-methyl-benzene-thiol-ate ligand with the average Mn-Np and the apical Mn-S bond lengths being 2.160 (9) and 2.4642 (8) Å, respectively. Two tetra-hydro-furan solvent mol-ecules and a potassium cation chelated inside a [2.2.2]cryptand (4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo[8.8.8]hexa-cosa-ne) are also present.

SUBMITTER: Yuan Y 

PROVIDER: S-EPMC9462021 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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([2.2.2]Cryptand)potassium (4-methyl-benzene-thiol-ato)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyr-inato]manganate(II) tetra-hydro-furan disolvate.

Yuan Yiwen Y   Li Jianfeng J  

IUCrData 20220308 Pt 3

Single crystals of the title compound, [K(C<sub>18</sub>H<sub>36</sub>N<sub>2</sub>O<sub>6</sub>)][Mn(C<sub>44</sub>H<sub>24</sub>Cl<sub>4</sub>N<sub>4</sub>)(C<sub>7</sub>H<sub>7</sub>S)]·2C<sub>4</sub>H<sub>8</sub>O, were obtained by the solvent evaporation method. The Mn<sup>II</sup> cation is coordinated by four pyrrole N atoms (N<sub>p</sub>) of the porphyrin ring and one S atom of the apical 4-methyl-benzene-thiol-ate ligand with the average Mn-N<sub>p</sub> and the apical Mn-S bond length  ...[more]

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