Dataset Information
(Cobaltoceniumyl-amido)-pyridinium hexa-fluorido-phosphate.
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ABSTRACT:
SUBMITTER: Menia D
PROVIDER: S-EPMC9462337 | biostudies-literature | 2021 May
REPOSITORIES: biostudies-literature
Publications
(Cobaltoceniumyl-amido)-pyridinium hexa-fluorido-phosphate.
IUCrData 20210501 Pt 5
The title compound, [Co(C<sub>5</sub>H<sub>5</sub>)(C<sub>10</sub>H<sub>9</sub>N<sub>2</sub>)]PF<sub>6</sub>, was synthesized from deproton-ated 1-amino-pyridinium iodide, followed by microwave-assisted nucleophilic aromatic substitution of iodo-cobaltocenium iodide. After anion exchange with potassium hexa-fluorido-phosphate, the title compound crystallizes as orange prisms in the space group <i>Pc</i>. This very stable pyridine nitrene adduct is the first example of a cobaltocenium derivative, ...[more]