Dataset Information

Membranes Based on Polyvinylidene Fluoride and Radiation-Grafted Sulfonated Polystyrene and Their Performance in Proton-Exchange Membrane Fuel Cells.

ABSTRACT: Proton-exchange membranes based on gamma-irradiated films of PVDF and radiation-grafted sulfonated polystyrene with an ion-exchange capacity of 1.8 meq/g and crosslinking degrees of 0 and 3% were synthesized. A solvent-free, environmentally friendly method of styrene grafting from its aqueous emulsion, with a styrene content of only 5 vol.% was used. Energy dispersive X-ray mapping analysis showed that the grafted sulfonated polystyrene is uniformly distributed throughout the membrane thickness. The obtained materials had a proton conductivity up to 132 mS/cm at 80 °C and a hydrogen permeability of up to 5.2 cm²/s at 30 °C, which significantly exceeded similar values for Nafion^®-212 membranes. The resulting membranes exhibited a H₂/O₂ fuel cell peak power density of up to 0.4 W/cm² at 65 °C. Accelerated stability tests showed that adding a crosslinking agent could significantly increase the stability of the membranes in the fuel cells. The thermal properties and crystallinity of the membranes were investigated through differential scanning calorimetry and X-ray powder diffraction methods. The conductivity, water uptake, and mechanical properties of the membranes (stress-strain curves) were also characterized.

SUBMITTER: Golubenko DV

PROVIDER: S-EPMC9504926 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature

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Membranes Based on Polyvinylidene Fluoride and Radiation-Grafted Sulfonated Polystyrene and Their Performance in Proton-Exchange Membrane Fuel Cells.

Golubenko Daniil V DV Korchagin Oleg V OV Voropaeva Daria Yu DY Bogdanovskaya Vera A VA Yaroslavtsev Andrey B AB

Polymers 20220914 18

Proton-exchange membranes based on gamma-irradiated films of PVDF and radiation-grafted sulfonated polystyrene with an ion-exchange capacity of 1.8 meq/g and crosslinking degrees of 0 and 3% were synthesized. A solvent-free, environmentally friendly method of styrene grafting from its aqueous emulsion, with a styrene content of only 5 vol.% was used. Energy dispersive X-ray mapping analysis showed that the grafted sulfonated polystyrene is uniformly distributed throughout the membrane thickness. ...[more]

PMID: 36145977

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Project description:This work deals with the development of graphene oxide (GO)-based self-assembling membranes as possible innovative proton conductors to be used in polymer electrolyte membrane fuel cells (PEMFCs). Nowadays, the most adopted electrolyte is Chemours' Nafion; however, it reveals significant deficiencies such as strong dehydration at high temperature and low humidity, which drastically reduces its proton conductivity. The presence of oxygenated moieties in the GO framework makes it suitable for functionalization, which is required to enhance the promising, but insufficient, proton-carrying features of GO. In this study, sulfonic acid groups (-SO3H) that should favor proton transport were introduced in the membrane structure via a reaction between GO and concentrated sulfuric acid. Six acid-to-GO molar ratios were adopted in the synthesis procedure, giving rise to final products with different sulfonation degrees. All the prepared samples were characterized by means of TGA, ATR-FTIR and Raman spectroscopy, temperature-dependent XRD, SEM and EDX, which pointed out morphological and microstructural changes resulting from the functionalization stage, confirming its effectiveness. Regarding functional features, electrochemical impedance spectroscopy (EIS) as well as measurements of ion exchange capacity (IEC) were carried out to describe the behavior of the various samples, with pristine GO and commercial Nafion® 212 used as reference. EIS tests were performed at five different temperatures (20, 40, 60, 80 and 100 °C) under high (95%) and medium (42%) relative humidity conditions. Compared to both GO and Nafion® 212, the sulfonated specimens demonstrate an increase in the number of ion-carrying groups, as proved by both IEC and EIS tests, which reveal the enhanced proton conductivity of these novel membranes. Specifically, an acid-to-GO molar ratio of 10 produces a six-fold improvement of IEC (4.23 meq g-1) with respect to pure GO (0.76 meq g-1), while a maximum eight-fold improvement (5.72 meq g-1) is achieved in SGO-15.

Dataset Information

Membranes Based on Polyvinylidene Fluoride and Radiation-Grafted Sulfonated Polystyrene and Their Performance in Proton-Exchange Membrane Fuel Cells.

Publications

Membranes Based on Polyvinylidene Fluoride and Radiation-Grafted Sulfonated Polystyrene and Their Performance in Proton-Exchange Membrane Fuel Cells.

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