Relationship between hydrothermal temperatures and structural properties of CeO₂ and enhanced catalytic activity of propene/toluene/CO oxidation by Au/CeO₂ catalysts.

ABSTRACT: A simple hydrothermal synthesis of CeO₂ was implemented to obtain a series of CeO₂-supported gold (Au) catalysts, used for the total oxidation of propene/toluene/CO gas mixtures and the oxidation of CO. CeO₂ preparation started from a cerium hydrogen carbonate precursor using a range of different hydrothermal temperatures (HT) from 120 to 180°C. High-resolution transmission electron microscopy, X-ray diffraction, and H₂-temperature-programmed reduction data indicated that CeO₂ morphology varied with the HT, and was composed of the more active (200) surface. Following Au deposition onto the CeO₂ support, this active crystal plane resulted in the most widely dispersed Au nanoparticles on the CeO₂ support. The catalytic performance of the CeO₂-supported Au catalysts for both oxidation reactions improved as the reducibility increased to generate lattice oxygen vacancies and the number of adsorbed peroxide species on the CeO₂ support increased due to addition of Au. The Au catalyst on the CeO₂ support prepared at 120°C was the most active in both propene/toluene/CO oxidation and independent CO oxidation.

SUBMITTER: Eaimsumang S 

PROVIDER: S-EPMC9532521 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature