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Synthetic study toward the diterpenoid aberrarone.


ABSTRACT: An approach to aberrarone, an antimalarial diterpenoid natural product with tetracyclic skeleton is reported. Key to the stereoselective preparation of the 6-5-5 tricyclic skeleton includes the mediation of Nagata reagent for constructing the C1 all-carbon quaternary centers and gold-catalyzed cyclopentenone synthesis through C-H insertion.

SUBMITTER: Shi L 

PROVIDER: S-EPMC9727272 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Synthetic study toward the diterpenoid aberrarone.

Shi Liang L   Gao Zhiyu Z   Li Yiqing Y   Dai Yuanhao Y   Liu Yu Y   Shi Lili L   Hao Hong-Dong HD  

Beilstein journal of organic chemistry 20221130


An approach to aberrarone, an antimalarial diterpenoid natural product with tetracyclic skeleton is reported. Key to the stereoselective preparation of the 6-5-5 tricyclic skeleton includes the mediation of Nagata reagent for constructing the C1 all-carbon quaternary centers and gold-catalyzed cyclopentenone synthesis through C-H insertion. ...[more]

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