Dataset Information

BiVO₄-Deposited MIL-101-NH₂ for Efficient Photocatalytic Elimination of Cr(VI).

ABSTRACT: In this study, a flower-like BiVO₄/MIL-101-NH₂ composite is synthesized by a facile and surfactant-free process. The -COO^--Bi³⁺ ionic bond construction was conductive to enhance the interface affinity between BiVO₄ and MIL-101-NH₂. Due to the highly efficient light capture and sufficient electron traps induced by oxygen vacancies and the formation of a heterostructure, the improved separation and transportation rates of charge carriers are realized. In addition, the MIL-101-NH₂/BiVO₄ composite is favorable for Cr(VI) photocatalytic removal (91.2%). Moreover, FNBV-3 (Fe/Bi = 0.25) also exhibited an excellent reusability after five cycles.

SUBMITTER: Sun H

PROVIDER: S-EPMC9921149 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Publications

BiVO4-Deposited MIL-101-NH2 for Efficient Photocatalytic Elimination of Cr(VI).

Sun Huiwen H Dai Qihang Q Liu Ju J Zhou Tiantian T Chen Muhua M Cai Zhengchun Z Zhu Xinbao X Fu Bo B

Molecules (Basel, Switzerland) 20230126 3

In this study, a flower-like BiVO4/MIL-101-NH2 composite is synthesized by a facile and surfactant-free process. The -COO--Bi3+ ionic bond construction was conductive to enhance the interface affinity between BiVO4 and MIL-101-NH2. Due to the highly efficient light capture and sufficient electron traps induced by oxygen vacancies and the formation of a heterostructure, the improved separation and transportation rates of charge car ...[more]

PMID: 36770885

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Project description:In this study, hybrids of nanoporous MIL-101(Cr) and MIL-53(Al) were synthesized using a hydrothermal method for various time periods, ranging from 8 to 40 h. The prepared materials were characterized by powder X-ray diffraction (PXRD) and elemental analysis, and their specific surface areas were measured by N2 sorption at 77 K using the Brunauer-Emmett-Teller (BET) method. To investigate the practical application of these materials, the pure carbon dioxide and methane adsorption capacities of the samples were determined using the volumetric method. The Langmuir model was used to fit the CO2 and CH4 isotherms. Extended Langmuir (EL) equations and the ideal adsorbed solution theory (IAST) models were used to obtain the CO2/CH4 selectivity. The sample with the highest BET specific surface area was selected as a candidate for further investigations. The thermal stability of the selected sample was investigated by thermogravimetric analysis (TGA). Scanning electron microscopy (SEM) was used to characterize the sample morphology. XRD results showed that the sample synthesized over the shortest time corresponded to MIL-101(Cr), while the sample synthesized over the longest time was in agreement with MIL-53(Al). Samples synthesized for time periods between these two limits were assumed to be composites of both MIL-53(Al) and MIL-101(Cr). TGA results indicated that the hybrid materials were thermally stable at temperatures about 100 °C higher than for pure MIL-101(Cr). The BET specific surface area (1746 m2 g-1) and CO2 adsorption capacity (16 mmol g-1) of the selected hybrid sample were about 50% and 35% higher, respectively, compared with those of pure MIL-53(Al), but 30% and 20% lower, respectively, compared with those of pure MIL-101(Cr). Binary adsorption modeling showed the high selectivity of the MIL-101(Cr) and MIL-53(Al) hybrid material for CO2 with a minimum separation factor of about 60 at 298 K. This value was much higher than those reported previously and those observed in this work for the original MIL-101(Cr) or MIL-53(Al). These results demonstrated that the hybrid of MIL-101(Cr) and MIL-53(Al) was a promising material for selective CO2 capture from natural and biogas.

Dataset Information

BiVO₄-Deposited MIL-101-NH₂ for Efficient Photocatalytic Elimination of Cr(VI).

Publications

BiVO<sub>4</sub>-Deposited MIL-101-NH<sub>2</sub> for Efficient Photocatalytic Elimination of Cr(VI).

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