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Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates(III) and Mn(III) Complex.

ABSTRACT: Two novel 1D heterobimetallic compounds {[Mn^III(SB²⁺)M^III(CN)₆]·4H₂O}_n (SB²⁺ = N,N'-ethylenebis(5-trimethylammoniomethylsalicylideneiminate) based on orbitally degenerate cyanidometallates [Os^III(CN)₆]^3- (1) and [Ru^III(CN)₆]^3- (2) and Mn^III Schiff base complex were synthesized and characterized structurally and magnetically. Their crystal structures consist of electrically neutral, well-isolated chains composed of alternating [M^III(CN)₆]^3- anions and square planar [Mn^III(SB²⁺)]³⁺ cations bridged by cyanide groups. These -ion magnetic anisotropy of Mn^III centers. These results indicate that the presence of compounds exhibit single-chain magnet (SCM) behavior with the energy barriers of Δτ₁/k_B = 73 K, Δτ₂/k_B = 41.5 K (1) and Δτ₁/k_B = 51 K, Δτ₂ = 27 K (2). Blocking temperatures of T_B = 2.8, 2.1 K and magnetic hysteresis with coercive fields (at 1.8 K) of 8000, 1600 Oe were found for 1 and 2, respectively. Theoretical analysis of the magnetic data reveals that their single-chain magnet behavior is a product of a complicated interplay of extremely anisotropic triaxial exchange interactions in M^III(4d/5d)-CN-Mn^III fragments: -J_xS_M^xS_Mn^x-J_yS_M^yS_Mn^y-J_zS_M^zS_Mn^z, with opposite sign of exchange parameters J_x = -22, J_y = +28, J_z = -26 cm^-1 and J_x = -18, J_y = +20, J_z = -18 cm^-1 in 1 and 2, respectively) and single orbitally degenerate [Os^III(CN)₆]^3- and [Ru^III(CN)₆]^3- spin units with unquenched orbital angular momentum in the chain compounds 1 and 2 leads to a peculiar regime of slow magnetic relaxation, which is beyond the scope of the conventional Glaubers's 1D Ising model and anisotropic Heisenberg model.

SUBMITTER: Mironov VS

PROVIDER: S-EPMC9921754 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates(III) and Mn(III) Complex.

Mironov Vladimir S VS Peresypkina Eugenia V EV Vostrikova Kira E KE

Molecules (Basel, Switzerland) 20230203 3

Two novel 1D heterobimetallic compounds {[MnIII(SB2+)MIII(CN)6]·4H2O}n (SB2+ = N,N'-ethylenebis(5-trimethylammoniomethylsalicylideneiminate) based on orbitally degenerate cyanidometallates [OsIII(CN)6]3- (1) and [RuIII(CN)6]3- (2) and MnIII Schiff base complex were synthesized and characterized structurally and magnetically ...[more]

PMID: 36771182

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Dataset Information

Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates(III) and Mn(III) Complex.

Publications

Interplay of Anisotropic Exchange Interactions and Single-Ion Anisotropy in Single-Chain Magnets Built from Ru/Os Cyanidometallates(III) and Mn(III) Complex.

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