Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
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ABSTRACT:
SUBMITTER: Emerson-King J
PROVIDER: S-EPMC9933454 | biostudies-literature | 2023 Feb
REPOSITORIES: biostudies-literature
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Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
Emerson-King Jack J Pan Sudip S Gyton Matthew R MR Tonner-Zech Ralf R Chaplin Adrian B AB
Chemical communications (Cambridge, England) 20230216 15
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2'-biphenyl)(CxP<sub>2</sub>)(N<sub>2</sub>)]<sup>+</sup> are described, where CxP<sub>2</sub> is a <i>trans</i>-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle. ...[more]
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