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Interfacial Synthesis of an Ultrathin Two-Dimensional Polymer Film via [2 + 2] Photocycloaddition.

ABSTRACT: A carbon-carbon-linked, ultrathin, two-dimensional (2D) polymer film was prepared at the air/water interface through photochemically triggered [2 + 2] cycloaddition. The preorganization of the monomers on the water surface and the subsequent photo-polymerization led to the successful preparation of the ultrathin 2D polymer film. The obtained film is continuous, free standing, and has a large area (over 50 μm²). Transmission electron microscopy (TEM) and atomic force microscopy (AFM) give clear evidence of the ultrathin film morphology. Raman spectroscopy and X-ray photoelectron spectroscopy (XPS) indicate successful photo-induced [2 + 2] polymerization.

SUBMITTER: Ban Y

PROVIDER: S-EPMC9965025 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Interfacial Synthesis of an Ultrathin Two-Dimensional Polymer Film via [2 + 2] Photocycloaddition.

Ban Yanqi Y Wang Hui H Xiao Zixuan Z Sun Lishui L Pan Qingyan Q Zhao Yingjie Y

Molecules (Basel, Switzerland) 20230217 4

A carbon-carbon-linked, ultrathin, two-dimensional (2D) polymer film was prepared at the air/water interface through photochemically triggered [2 + 2] cycloaddition. The preorganization of the monomers on the water surface and the subsequent photo-polymerization led to the successful preparation of the ultrathin 2D polymer film. The obtained film is continuous, free standing, and has a large area (over 50 μm<sup>2</sup>). Transmission electron microscopy (TEM) and atomic force microscopy (AFM) g ...[more]

PMID: 36838919

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