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Suzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates.

ABSTRACT: [reaction: see text] The palladium-catalyzed cross-coupling of potassium aryltrifluoroborates with benzylic halides occurs in good yield with high functional group tolerance. The increased stability of potassium aryltrifluoroborates compared to other boron coupling partners makes this an effective route to functionalized methylene-linked biaryl systems.

SUBMITTER: Molander GA 

PROVIDER: S-EPMC2515367 | biostudies-other | 2006 Nov

REPOSITORIES: biostudies-other

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Suzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates.

Molander Gary A GA   Elia Maxwell D MD  

The Journal of organic chemistry 20061101 24

[reaction: see text] The palladium-catalyzed cross-coupling of potassium aryltrifluoroborates with benzylic halides occurs in good yield with high functional group tolerance. The increased stability of potassium aryltrifluoroborates compared to other boron coupling partners makes this an effective route to functionalized methylene-linked biaryl systems. ...[more]

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