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Organometallic ruthenium complexes with thiosemicarbazone ligands: Synthesis, structure and cytotoxicity of [(eta-p-cymene)Ru(NS)Cl] (NS = 9-anthraldehyde thiosemicarbazones).


ABSTRACT: A series of half-sandwich arene-ruthenium complexes of the type [(eta(6)-p-cymene) Ru(thiosemicarbazone)Cl](+) have been synthesized and their biological activity investigated. The first structurally characterized arene-ruthenium half-sandwich complex with a thiosemicarbazone ligand is reported.

SUBMITTER: Beckford FA 

PROVIDER: S-EPMC2769075 | biostudies-other | 2009 Nov

REPOSITORIES: biostudies-other

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Organometallic ruthenium complexes with thiosemicarbazone ligands: Synthesis, structure and cytotoxicity of [(eta-p-cymene)Ru(NS)Cl] (NS = 9-anthraldehyde thiosemicarbazones).

Beckford Floyd A FA   Leblanc Gabriel G   Thessing Jeffrey J   Shaloski Michael M   Frost Brian J BJ   Li Liya L   Seeram Navindra P NP  

Inorganic chemistry communications 20091101 11


A series of half-sandwich arene-ruthenium complexes of the type [(eta(6)-p-cymene) Ru(thiosemicarbazone)Cl](+) have been synthesized and their biological activity investigated. The first structurally characterized arene-ruthenium half-sandwich complex with a thiosemicarbazone ligand is reported. ...[more]

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