ABSTRACT: Taiyuan, the capital of Shanxi province, China, is one of the most polluted cities in the world. To characterize the ambient particulate pollution, samples of particulates with aerodynamic diameter less than 10 microm (PM(10)) were collected during a 6-day campaign. Individual particles were analyzed by Scanning Electron Microscope with Energy-Dispersive Spectrometer (SEM-EDS) to determine their chemical composition. Meanwhile, photomicrographs were obtained from SEM to aid in particles' source identification. The lumped data from SEM-EDS were subjected to hierarchical cluster analysis (HCA) to sort out particle types chemically. HCA combined with SEM photomicrographs allowed us to identify 20 different particle types, namely (in order of particle frequency), soil/fly ash particles, coal-burning, sulfur-rich, and iron-rich particles, gypsum, syngenite, quartz, cement, silicon sulfide, siliconferro alloy, calcium-rich particles, ferrochromium alloy, ammonium sulfate and chloride, iron-zinc, ammonium chloride, molybdenum-rich, potassium sulfate, dolomite, lead sulfate, and copper-rich particles. Their possible origins and pathways are suggested. The majority of the particles seem to originate from coal combustion, which conforms to Taiyuan's industrial structure.
