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Femtosecond quantum control of molecular bond formation.

ABSTRACT: Ultrafast lasers are versatile tools used in many scientific areas, from welding to eye surgery. They are also used to coherently manipulate light-matter interactions such as chemical reactions, but so far control experiments have concentrated on cleavage or rearrangement of existing molecular bonds. Here we demonstrate the synthesis of several molecular species starting from small reactant molecules in laser-induced catalytic surface reactions, and even the increase of the relative reaction efficiency by feedback-optimized laser pulses. We show that the control mechanism is nontrivial and sensitive to the relative proportion of the reactants. The control experiments open up a pathway towards photocatalysis and are relevant for research in physics, chemistry, and biology where light-induced bond formation is important.

SUBMITTER: Nuernberger P

PROVIDER: S-EPMC2890816 | biostudies-other | 2010 Jun

REPOSITORIES: biostudies-other

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Femtosecond quantum control of molecular bond formation.

Nuernberger Patrick P Wolpert Daniel D Weiss Horst H Gerber Gustav G

Proceedings of the National Academy of Sciences of the United States of America 20100526 23

Ultrafast lasers are versatile tools used in many scientific areas, from welding to eye surgery. They are also used to coherently manipulate light-matter interactions such as chemical reactions, but so far control experiments have concentrated on cleavage or rearrangement of existing molecular bonds. Here we demonstrate the synthesis of several molecular species starting from small reactant molecules in laser-induced catalytic surface reactions, and even the increase of the relative reaction eff ...[more]

PMID: 20505117

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