Unknown

Dataset Information

0

Redetermination of dicerium(III) tris-(sulfate) tetra-hydrate.


ABSTRACT: Ce(2)(SO(4))(3)(H(2)O)(4) was obtained hydro-thermally from an aqueous solution of cerium(III) oxide, trimethyl-amine and sulfuric acid. The precision of the structure determination has been significantly improved compared with the previous result [Dereigne (1972 ?). Bull. Soc. Fr. Mineral. Cristallogr.95, 269-280]. The coordination about the two Ce atoms is achieved by seven and six bridging O atoms from sulfate anions. Each S atom makes four S-O-Ce linkages through bridging O atoms. The coordination sphere of each Ce is completed by two water molecules, which act as terminal ligands.

SUBMITTER: Xu X 

PROVIDER: S-EPMC2914879 | biostudies-other | 2007

REPOSITORIES: biostudies-other

altmetric image

Publications

Redetermination of dicerium(III) tris-(sulfate) tetra-hydrate.

Xu Xin X  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


Ce(2)(SO(4))(3)(H(2)O)(4) was obtained hydro-thermally from an aqueous solution of cerium(III) oxide, trimethyl-amine and sulfuric acid. The precision of the structure determination has been significantly improved compared with the previous result [Dereigne (1972 ▶). Bull. Soc. Fr. Mineral. Cristallogr.95, 269-280]. The coordination about the two Ce atoms is achieved by seven and six bridging O atoms from sulfate anions. Each S atom makes four S-O-Ce linkages through bridging O atoms. The coordi  ...[more]

Similar Datasets

| S-EPMC3099932 | biostudies-literature
| S-EPMC2959986 | biostudies-literature
| S-EPMC3007973 | biostudies-literature
| S-EPMC3588511 | biostudies-literature
| S-EPMC4645054 | biostudies-literature
| S-EPMC3200703 | biostudies-literature
| S-EPMC2959531 | biostudies-literature
| S-EPMC3099756 | biostudies-literature
| S-EPMC2962004 | biostudies-literature
| S-EPMC2979795 | biostudies-literature