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Dicaesium tetra-chlorido-dioxido-plutonate(VI).

ABSTRACT: The anion of the title complex, Cs(2)[PuCl(4)O(2)], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido-plutonate(VI) anion. Principal bond lengths include Pu-O = 1.752?(3)?Å and Pu-Cl = 2.6648?(8)?Å.

SUBMITTER: Wilkerson MP 

PROVIDER: S-EPMC2914883 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Dicaesium tetra-chlorido-dioxido-plutonate(VI).

Wilkerson Marianne P MP   Scott Brian L BL  

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

The anion of the title complex, Cs(2)[PuCl(4)O(2)], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido-plutonate(VI) anion. Principal bond lengths include Pu-O = 1.752 (3) Å and Pu-Cl = 2.6648 (8) Å. ...[more]