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Dichlorido(di-2-pyridyl sulfide-?N,N')zinc(II).

ABSTRACT: The crystal structure of the title compound, [ZnCl(2)(C(10)H(8)N(2)S)], consists of a six-membered chelate ring in which the Zn atom is approximately tetra-hedrally coordinated by two chloride ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 50.4 (1)°.

SUBMITTER: Wriedt M

PROVIDER: S-EPMC2914903 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Dichlorido(di-2-pyridyl sulfide-κN,N')zinc(II).

Wriedt Mario M Jess Inke I Näther Christian C

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The crystal structure of the title compound, [ZnCl(2)(C(10)H(8)N(2)S)], consists of a six-membered chelate ring in which the Zn atom is approximately tetra-hedrally coordinated by two chloride ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 50.4 (1)°. ...[more]

PMID: 21200458

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Dibromido(di-2-pyridyl sulfide-κN,N')zinc(II).

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Project description:In the heteromolecular title structure, C(10)H(8)N(2)S·C(8)H(6)O(4), the two components are linked by O-H⋯N hydrogen bonds to form a one-dimensional chain. These chains are further inter-connected by weak inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions to generate a three-dimensional supra-molecular structure.

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Project description:In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol-ecules are stacked in columns along the c axis and display inter-molecular ?-? inter-actions between the six-membered rings, the shortest centroid-centroid distance being 3.553?(3)Å. Inter-molecular C-H?Cl contacts are also noted.

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