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(?-Benzene)(2,2'-bipyridine-?N,N')chloridoruthenium(II) chloride methanol sesquisolvate.

ABSTRACT: In the title compound, [RuCl(C(6)H(6))(C(10)H(8)N(2))]Cl·1.5CH(4)O, the Ru(II) atom is in a distorted octa-hedral environment coordinated by an ?(6)-benzene ring, a chelating 2,2'-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol mol-ecules, one of which is disordered about a centre of inversion with an occupancy of 0.5. It is an example of a ruthenium complex with a less sterically congested environment than in similar derivatives. In the crystal structure, O-H?Cl hydrogen bonds, together with ?-? stacking inter-actions [centroid-centroid distances of 3.472Å(2)?Å], stabilize the structure.

SUBMITTER: Polson MI

PROVIDER: S-EPMC2915169 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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(η-Benzene)(2,2'-bipyridine-κN,N')chloridoruthenium(II) chloride methanol sesquisolvate.

Polson Matthew I J MI

Acta crystallographica. Section E, Structure reports online 20071221 Pt 1

In the title compound, [RuCl(C(6)H(6))(C(10)H(8)N(2))]Cl·1.5CH(4)O, the Ru(II) atom is in a distorted octa-hedral environment coordinated by an η(6)-benzene ring, a chelating 2,2'-bipyridine ligand and a chloride ion. The asymmetric unit is completed by a chloride anion and two methanol mol-ecules, one of which is disordered about a centre of inversion with an occupancy of 0.5. It is an example of a ruthenium complex with a less sterically congested environment than in similar derivatives. In th ...[more]

PMID: 21200593

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