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Dibenzyl penta-thio-dicarbonate.

ABSTRACT: In the title compound, C(16)H(14)S(5), the non-bonded intra-molecular distances between the non-terminal S atoms are 2.808?(16) and 2.784?(16)?Å, shorter than the typical distance of 2.9?Å. One phenyl ring participates in an offset ?-? inter-action with another phenyl ring related by a centre of inversion; the inter-planar distance is 3.41?(2)?Å. The crystal structure also exhibits edge-to-face C-H?? stacking of the phenyl rings, thus forming a herring-bone packing motif.

SUBMITTER: Weber WG

PROVIDER: S-EPMC2915307 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Dibenzyl penta-thio-dicarbonate.

Weber Wolfgang G WG McLeary James B JB Gertenbach Jan-André JA Loots Leigh L

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

In the title compound, C(16)H(14)S(5), the non-bonded intra-molecular distances between the non-terminal S atoms are 2.808 (16) and 2.784 (16) Å, shorter than the typical distance of 2.9 Å. One phenyl ring participates in an offset π-π inter-action with another phenyl ring related by a centre of inversion; the inter-planar distance is 3.41 (2) Å. The crystal structure also exhibits edge-to-face C-H⋯π stacking of the phenyl rings, thus forming a herring-bone packing motif. ...[more]

PMID: 21200815

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